Vol.:(0123456789) 1 3
Journal of Inorganic and Organometallic Polymers and Materials
https://doi.org/10.1007/s10904-020-01713-4
Biological Compound Capping of Silver Nanoparticle with the Seed
Extracts of Blackcumin (Nigella sativa): A Potential Antibacterial,
Antidiabetic, Anti‑infammatory, and Antioxidant
Sekar Vijayakumar
1,2
· Mani Divya
2
· Baskaralingam Vaseeharan
2
· Jingdi Chen
1
· Muniyandi Biruntha
3
·
Luciano Paulino Silva
4
· Esteban F. Durán‑Lara
5,6
· Krishnan Shreema
7
· Shivendu Ranjan
8
· Nandita Dasgupta
8
Received: 21 June 2020 / Accepted: 13 August 2020
© Springer Science+Business Media, LLC, part of Springer Nature 2020
Abstract
It is a well explored facts that need of biosynthesized nanomaterials has emerged for its several advantages in biomedical
applications and the search for potential biosynthesized-nanomaterials is still ongoing. In this study an attempt was made to
meet the requirement of potential biosynthesized-silver nanoparticles using the aqueous seed extract of N. sativa (Bc-AgNPs).
X-ray powder difraction (XRD) confrms the biosynthesis of silver nanoparticle (supports the observation of UV–Vis
spectroscopy) with face centred cubic structure. Fourier-transform infrared spectroscopy (FTIR) confrms the capping of
the active ingredients of seed extract and further the average size of 34 nm was confrmed by high-resolution transmission
electron microscopy (HR-TEM) and energy dispersive X-ray analysis (EDX) confrms the purity of Bc-AgNPs. Due to the
capping of the active ingredients of seed extract, the Bc-AgNPs have shown signifcant antibacterial activity against Gram
negative bacteria and at the lower concentration of 100 µg*ml
−1
it has 89% scavenging activity against free radicals. A strong
anti-infammatory (membrane stabilization) activity towards RBCs (98% at 100 µg*ml
−1
) was recorded when compared to
the positive control (aceclofenac). In addition to the previous activities, a greater inhibition of carbohydrate hydrolyzing
enzymes such as α-amylase, α-glucosidase and DPP-IV highlighted the antidiabetic potential of these green synthesized
AgNPs. Overall, the efcient bioactivities of Bc-AgNPs advocates its future potential in biomedical products.
Keywords Diabetes mellitus · Nigella sativa · Silver nanoparticles · Antioxidant · Anti-infammatory
Abbreviations
AgNO
3
Silver nitrate
ATCC American Type Culture Collection
BC Black cumin
Electronic supplementary material The online version of this
article (https://doi.org/10.1007/s10904-020-01713-4) contains
supplementary material, which is available to authorized users.
* Sekar Vijayakumar
vijaysekar05@gmail.com; sekarvijayakumar@sdu.edu.cn
Jingdi Chen
jdchen@sdu.edu.cn
Luciano Paulino Silva
luciano.paulino@embrapa.br
Shivendu Ranjan
shivendur@uj.ac.za; shivenduranjan@gmail.com
1
Marine College, Shandong University, Weihai 264209,
People’s Republic of China
2
Nanobiosciences and Nanopharmacology Division,
Biomaterials and Biotechnology in Animal Health
Lab, Department of Animal Health and Management,
Alagappa University, Science campus 6th Floor, Karaikudi,
Tamil Nadu 630004, India
3
Vermiculture Technology Lab, Department of Animal Health
and Management, Alagappa University, Science campus 6th
Floor, Karaikudi, Tamil Nadu 630004, India
4
Embrapa Genetic Resources and Biotechnology, PBI,
Laboratory of Nanobiotechnology (LNANO), Brasília,
DF 70770-917, Brazil
5
Bio & NanoMaterials Lab| Drug Delivery and Controlled
Release, Universidad de Talca, 3460000 Talca, Maule, Chile
6
Departamento de Microbiología, Facultad de Ciencias de la
Salud, Universidad de Talca, 3460000 Talca, Maule, Chile
7
Department of Physics, Sri Sarada College for Women
(Autonomous), Salem, Tamil Nadu 636016, India
8
Institute for Intelligent Systems, Faculty of Engineering
and the Built Environment, University of Johannesburg,
Johannesburg, South Africa