Nano-Structures & Nano-Objects 16 (2018) 180–184
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Nano-Structures & Nano-Objects
journal homepage: www.elsevier.com/locate/nanoso
Synthesis and magnetic dispersibility of magnetite decorated reduced
graphene oxide
Wasi Khan
a,
*, Avdesh Kumar Singh
b
, Swaleha Naseem
b
, Shahid Husain
a
, Mohd. Shoeb
c
,
M. Nadeem
b
a
Department of Physics, Aligarh Muslim University, Aligarh 202002, India
b
Department of Applied Physics, Z.H. College of Engg. & Technology, Aligarh Muslim University, Aligarh 202002, India
c
Department of Applied Chemistry, Z.H. College of Engg. & Technology, Aligarh Muslim University, Aligarh 202002, India
graphical abstract
article info
Article history:
Received 1 November 2017
Received in revised form 8 May 2018
Accepted 13 June 2018
Keywords:
Graphene oxide
Magnetite nanoparticles
Electron microscopy
FTIR
Magnetic dispersibility
abstract
In the present work, we have successfully synthesized graphene oxide (GO) and reduced graphene
oxide/magnetite (Gr@Fe
3
O
4
) nanocomposite (NC) via modified Hummers method and co-precipitation
process respectively. Microstructural and physico-chemical properties were investigated through various
analytical techniques. XRD and FTIR data analyses revealed highly pure nature of the samples without
any other impurity phases. Electron microscopy (SEM/TEM) images of the nanocomposite clearly exhibit
uniform and well disperse spherical nanoparticles (NPs) of Fe
3
O
4
over the surface of the graphene sheets.
UV-visible absorption spectroscopy indicates a red shift of the absorption band of Gr@Fe
3
O
4
NC as
compared to Fe
3
O
4
NPs that suggests π-π noncovalent electrostatic interaction between the magnetic
NPs and the graphene surface. The magnetic dispersibility of the NC was also explored using an external
magnetic field produced by the simple bar magnets. The results affirm a higher magnetic dispersibility
nature of the Gr@Fe
3
O
4
NC than the graphene oxide and Fe
3
O
4
NPs. These behaviour of the NC can be
ascribed to synergistic structural and functional effect of Fe
3
O
4
nanoparticles conjugate with graphene
sheet.
© 2018 Elsevier B.V. All rights reserved.
*
Corresponding author.
E-mail address: wasiamu@gmail.com (W. Khan).
1. Introduction
Graphene has attracted tremendous attention due to its out-
standing properties and potential applications. More recently,
graphene based nanocomposites exhibit exceptional properties
https://doi.org/10.1016/j.nanoso.2018.06.003
2352-507X/© 2018 Elsevier B.V. All rights reserved.