© 2021 Authors. This is an Open Access article distributed under the terms and conditions of
the Creative Commons Attribution-NonCommercial 4.0 International License
(http://creativecommons.org/licenses/by-nc/4.0/).
Oil Shale, 2021, Vol. 38, No. 2, pp. 155–176 ISSN 0208-189X
doi: https://doi.org/10.3176/oil.2021.2.04 © 2021 Estonian Academy Publishers
* Corresponding author: e-mail mai.uibu@taltech.ee
The composition and properties of ash in the context of the
modernisation of oil shale industry
Mai Uibu
(a)*
, Kadriann Tamm
(a)
, Regiina Viires
(a)
, Janek Reinik
(b)
,
Peeter Somelar
(c)
, Lembi Raado
(d)
, Tiina Hain
(d)
, Rein Kuusik
(a)
,
Andres Trikkel
(a)
(a)
Laboratory of Inorganic Materials, Department of Materials and Environmental
Technology, Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn,
Estonia
(b)
National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, 12618
Tallinn, Estonia
(c)
Department of Geology, University of Tartu, Ravila 14A, 50411 Tartu, Estonia
(d)
Building Lifecycle Research Group, Department of Civil Engineering and
Architecture, Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn,
Estonia
Received 14.11.2019, accepted 16.05.2021, available online 10.06.2021
Abstract. The modernisation of the oil shale (OS) industry in Estonia over the
last decade has also led to signifcant changes in the composition and binding
properties of the ash generated as a by-product. These changes also infuence
the environmental impact that the ash can have. In the current investigation,
oil shale ash (OSA) samples were collected from different points along the
ash separation systems of a large pulverized fuel combustion plant (LCP),
various points in a circulating fuidized bed (CFB) combustion plant, and from
an oil shale pyrolysis plant that utilises oil shale to produce liquid fuels. The
results obtained can be used for optimising the deposition conditions, as well
as guiding utilisation-recycling processes for ash generated from changing
oil shale composition and characteristics. When it comes to developing the
circular economy aspects of oil shale utilisation, mapping out the properties
of OSA is crucial.
Keywords: oil shale ash, circular economy, binding properties, leaching.
1. Introduction
Harmonised European environmental regulations are in a state of constant
development. Air emissions, energy effciency levels, resource effciency, use