208 Int. J. Environmental Technology and Management, Vol. 15, Nos. 3/4/5/6, 2012
Copyright © 2012 Inderscience Enterprises Ltd.
Photocatalytic degradation of supra black-T dye on
charcoal under sunlight
Reena Amatya Shrestha
Department of Civil and Environmental Engineering,
Lehigh University,
Bethlehem, PA, USA
Email: reenashrestha@yahoo.com
Mika Sillanpää
Department of Environmental Sciences,
University of Eastern Finland,
Patteristonkatu 1, FI-50100 Mikkeli, Finland
and
Faculty of Technology,
Lappeenranta University of Technology,
Patteristonkatu 1, FI-50100 Mikkeli, Finland
Email: mika.sillanpaa@uef.fi
Jarina Joshi
Department of Biotechnology,
Tribhuwan University,
Kirtipur, Kathmandu, Nepal
Email: jarinarjoshi@yahoo.com
Ackmez Mudhoo*
Department of Chemical and Environmental Engineering,
University of Mauritius,
Réduit, Mauritius
Email: ackmezchem@yahoo.co.uk
*Corresponding author
Abstract: Azo dyes are used in many industries such as carpet manufacturing,
textiles, paint, ink, plastics and cosmetics production processes. The coloured
industrial effluent can pose serious problems in the aquatic environment. It is
possible to get complete mineralisation of organic pollutants in water by
photocatalysts. This study was carried out to examine the feasibility to remove
supra black-T dye from carpet dyeing wastewater by photocatalytic
degradation on Oak charcoal under sunlight. Adsorption efficiency of dye on
charcoal at various pH values and photodegradation with ZnO and TiO
2
catalysts were studied. The removal efficiency of charcoal alone was
28 mg dye/g charcoal at pH 8 and 25C in 60 min which was half that of
activated charcoal. Photocatalytic degradation and adsorption with TiO
2
and
ZnO under sunlight was faster and almost complete removal was observed in
shorter times.