Universal Journal of Materials Science 5(2): 38-51, 2017 http://www.hrpub.org
DOI: 10.13189/ujms.2017.050202
Effect of Single Walled Carbon Nanotubes (SWCNTs)
Addition during Field Activated Sparck Plasma Sinter
(FASPS) in the Ceramics Matrix Nanocomposites
(Mo
2
C)
1-x
(TiC)
x
(2≤x≤4): Physical, Mechanical Properties
and Sintering Behaviour
Badis Bendjemil
1,2,*
, Jacques G. Noudem
3
, Mohamed Mouyane
4
, Jérôme Bernard
4
, Jean Michel Reboul
4
,
Yannick Guhel
4
, David Houivet
4
1
DGM, FST, University of 8 Mai 1945 of Guelma, 24000 Guelma, Algeria
2
LASEA, DC, FS, University of Badji Mokhtar, 23000 Annaba, Algeria
3
ENSICAEN, 6, Boulevard Maréchal Juin, CS 45053 14050 Caen cedex 04, France
4
LUSAC, EA 4253, 60 rue Max Pol Fouchet, CS 20082, University of Caen Normandy, 50130 Cherbourg-Octeville, France
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the terms of the Creative Commons Attribution License 4.0 International License
Abstract Nanocomposites are wear resistant materials
used in cutting tool applications. The materials are
composed of ultrafine powder hard phase grains
surrounded by a tough binder phase carbon nanotubes
(Mo
2
C)
1-x
(TiC)
x
(2≤x≤4)//1Wt% SWCNTs. Composite
bicarbide Mo
2
C-TiC was rapidly synthesised and
simultaneously consolidated by Field activated sintering
technique (spark plasma sintering) at which the extensive
volume expansion occurred as a function of the volumic
fraction from 20 to 40 vol.% of TiC powders and 1 Wt.% of
SWCNTs as reinforcement of the CMNC’s. The sintered
powder mixture was examined by XRD patterns, the
morphology of the obtained phase was observed by SEM
and the phase compositions in different regions were
analyzed by EDX. The composites were processed using
Field Activated Sintering Technique, spark plasma
sintering (SPS) at temperatures in the range of
1700-1800°C with addicting of SWCNTs. The effects of
SWCNTs addition on phases morphology, microstructure
hardness and fracture toughness of the nanocomposite
were investigated. The best product contained 1.0 Wt.%
SWCNTs from (Mo
2
C)
1-x
(TiC)
x
, x= 0.2 which was
sintered at 1700°C, 70 MPa for 10 min, M
0.8
T
0.2
/ 1 Wt%
SWCNTs exhibit a better density, highest hardness and a
good ductility. Relative densification was achieved 99.5 %
from the theoretical and a good mechanical properties like
hardness and fracture toughness (K
IC
=5.6 Mpa m
1/2
) are
enhanced. The results were confirmed using Raman
spectroscopy.
Keywords (Mo
2
C)
1-x
(TiC)
x
(2≤x≤4)// 1 Wt%
SWCNTs, Ceramics Matrix Nanocomposites (CMNC’s),
Field Activated Sintering Technique (SPS), Physical
Properties, Mechanical Properties, Wear Resistant,
Microstructure-final, Raman Scattering
1. Introduction
Nanomaterials (defined as being in the size range
1-100 nm in at least one dimension) have been the subject
of extensive research in recent years due to their
extraordinary properties over their conventional
counterparts. For more than two decades, the topic of
nanomaterials’ development has been widely investigated
by many researchers aiming at exploring their potential and
finding suitable applications. Ultimately, they proved to be
beneficial in several applications in areas like surface
engineering, drug delivery, analytical chemistry, bio
encapsulation, Nano composite as well as in electronic,
magnetic, optical, and mechanical devices.
These applications do stimulate a great deal of research
interest amongst institutions and companies aiming at
capitalizing on their potential. However, there are still a
number of difficulties when it comes to processing of these
nanomaterials especially in fabricating final products as
these nanomaterials may lose their crystallite size along the
path of processing. These problems have to be tackled