ISSN 0020-4412, Instruments and Experimental Techniques, 2009, Vol. 52, No. 3, pp. 394–399. © Pleiades Publishing, Ltd., 2009.
Original Russian Text © V.M. Akimov, G. Witte, L.I. Kolesnikova, L.Yu. Rusin, J.P. Toennies, 2009, published in Pribory i Tekhnika Eksperimenta, 2009, No. 3, pp. 91–97.
394
The set of experimental methods used in studies
with molecular beams includes a wide circle of instru-
ments intended for generating various beams of various
atoms and molecules in a very wide range of kinetic
energies. One of the most urgent problems of this
important component of the molecular-beam method is
production of beams of free atoms and radicals possess-
ing a high chemical activity, for example, hydrogen and
oxygen atoms.
The most general requirement imposed on beam
sources is to reach a maximal intensity with as narrow
as possible velocity distribution of beam particles and
the possibility of changing their energies. To one or
another extent, this requirement can be satisfied using a
supersonic beam with production of atoms in the high-
frequency or microwave discharge plasma [1–3]. It is
evident that the higher the gas pressure in the discharge
region and the higher the efficient degree of dissocia-
tion, the more efficient these methods are. The latter
value is determined by the ratio of the dissociation and
atomic-recombination rates in the discharge region and
the gas expansion from the nozzle.
Paper [3] presents an atomic oxygen beam source
with a degree of é
2
dissociation of ~70% at a 350-Torr
pressure for a 5- to 10% mixture of oxygen and argon,
when the power in the discharge varies from 140 to
195 W. The generation of hydrogen atomic beams has
a substantial problem, and the working pressures in the
discharge at sufficiently high dissociation degrees are,
as a rule, no more than 1 Torr [4–8].
To initiate a stable discharge for generating an
atomic particle beam at increased pressures is more dif-
ficult than to do it at low pressures. These difficulties
are, in particular, related to the problem of matching the
impedances of the plasma and HF or microwave source
when the gas pressure and, hence, the plasma density
increases. In turn, the plasma characteristics substan-
tially depend on the gas composition, the reachable
plasma temperature, and another conditions. To
increase the efficiency of plasma sources of beams, it is
necessary to support the discharge directly near the
nozzle to decrease the degree of atomic recombination
before the gas-dynamic beam expansion occurs. In this
case, the temperature of the discharge-tube walls near
the nozzle should be in the optimal range, taking into
account the kinetics of reactions in the plasma and the
risk of melting of the nozzle orifice.
This work describes the results obtained in the pro-
cess of designing the source for generating and support-
ing stable microwave discharges in various gases and
their mixtures with noble gases in quartz tubes with a
2-mm inner diameter and a 0.15-mm-diameter nozzle.
The design is based on a surfatron [9, 10], in which the
discharge is initiated by a surface electromagnetic
wave. The advantage of such devices is that it is possi-
ble to produce a stable plasma in them at pressures of
up to several atmospheres, since, in this case, draw-
backs related to problems of sustaining an HF or micro-
wave discharge at elevated pressures in resonance
sources are eliminated. Characteristics of the discharge
initiated by the surface wave were intensively studied
for plasma of Ar [11]; He [12]; O
2
[13, 14]; N
2
[15];
He, Ne, and Ar [16]; H
2
[17, 18]; and é
2
–N
2
[19]; and
Ar–N
2
mixtures [20, 21].
GENERAL EXPERIMENTAL
TECHNIQUES
A Microwave Discharge Source Operating at Pressures of Several
Atmospheres
V. M. Akimov
a
, G. Witte
b
, L. I. Kolesnikova
a
, L. Yu. Rusin
a
, and J. P. Toennies
c
a
Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences,
Leninskii pr. 38, korp. 2, Moscow, 119334 Russia
b
Ruhr-Universität Bochum, Universitätsstraße 150, NBCF03/296, Bochum, D-44780 Germany
c
Max-Planck-Institut für Dynamik und Selbstorganisation, Bunsenstrasse 10, Gottingen, D-37073 Germany
Received July 11, 2008
Abstract—The design of a microwave source in which a discharge is initiated by an electromagnetic surface
wave at 2.45 GHz is described. A stable discharge was supported at a gas pressure p
0
exceeding the atmospheric
pressure in He, N
2
, and in H
2
–Ar, H
2
–He, and O
2
–He mixtures in a 2-mm inner diameter quartz tube with a
0.15-mm diameter nozzle at a 50- to 115-W microwave power. A degree of dissociation of up to 80% was
reached for pure H
2
at p
0
= 6 Torr and a 6% mixture of H
2
and He at p
0
= 50 Torr. When p
0
increases to 19 Torr
for H
2
and to 300 Torr for the mixture, the hydrogen-atom beam intensity, in spite of a decrease in the degree
of dissociation, increases due to narrowing of the beam particle velocity distribution.
PACS numbers: 52.50.Dg, 07.77.Gx, 39.10.+j
DOI: 10.1134/S0020441209030166