Open Journal of Applied Sciences, 2021, 11, 1-10
https://www.scirp.org/journal/ojapps
ISSN Online: 2165-3925
ISSN Print: 2165-3917
DOI: 10.4236/ojapps.2021.111001 Jan. 11, 2021 1 Open Journal of Applied Sciences
Metal Complexes with 8-Hydroxyquinoline:
Synthesis and In Vitro Antimicrobial Activity
Amira Cipurković
1
, Emir Horozić
2
, Snježana Marić
1
, Lejla Mekić
3
, Halid Junuzović
2
1
Faculty of Natural Sciences and Mathematics, University of Tuzla, Tuzla, Bosnia and Herzegovina
2
Faculty of Technology, University of Tuzla, Tuzla, Bosnia and Herzegovina
3
Faculty of Pharmacy, University of Tuzla, Tuzla, Bosnia and Herzegovina
Abstract
In this paper, three complexes with 8-hydroxyquinoline (8-HQ) were synthe-
sized, their spectral analysis was performed and the antimicrobial effect was
examined in vitro. The stoichiometric ratio of the complex was determined
conductometrically and spectrophotometrically. FTIR and UV/VIS spectros-
copy were used for structural characterization. Antimicrobial activity was ex-
amined by diffusion technique on selected gram-positive and gram-negative
bacteria, and C. albicans. Square planar and octahedral geometry complexes
were synthesized by mixing in a molar ratio of 1:2 (M:L). Based on the spec-
tral data, it is concluded that both oxygen and nitrogen atoms from 8-HQ are
involved in the formation of the complex. The antimicrobial activity of the
complexes is high, with zones of inhibition in the range of 15 - 28 mm. 8-HQ
was shown to have a significantly higher ability to inhibit the growth of the
tested microorganisms.
Keywords
8-HQ, Metal Complex, Antimicrobial Activity, In Vitro Study
1. Introduction
8-Hydroxyquinoline (8-HQ), also known as oxine or 8-quinolinol, is an alkaloid
which exists in plants of Asteraceae and Euphorbiaceae families [1] [2]. It is a mo-
noprotic, bidentate agent (Figure 1) that consists of two donor atoms, oxygen and
nitrogen [2]. The 8-HQ molecule acts as potent metal ion chelator, due to its oxygen
and nitrogen atoms [3]. Many studies on 8-hydroxyquinoline complexes were con-
ducted to date. After metal binding, 8-HQ changes its fluorescence. Construction of
How to cite this paper: Cipurković, A.,
Horozić, E., Marić, S., Mekić, L. and
Junuzović, H. (2021) Metal Complexes with
8-Hydroxyquinoline: Synthesis and In
Vitro Antimicrobial Activity. Open Journal
of Applied Sciences, 11, 1-10.
https://doi.org/10.4236/ojapps.2021.111001
Received: December 1, 2020
Accepted: January 8, 2021
Published: January 11, 2021
Copyright © 2021 by author(s) and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access