Review rticle
State-of-the-Art Graphene Synthesis Methods and
Environmental Concerns
Kaamil Edward ,
1
KabirMamun ,
1
SumeshNarayan ,
1
MansourAssaf ,
1
David Rohindra ,
2
andUpakaRathnayake
3,4
1
SchoolofInformationTechnologyEngineeringMathematicsandPhysics(STEMP), TeUniversityoftheSouthPacifc,Suva,Fiji
2
SchoolofBiologicalandChemicalSciences,FacultyofScienceTechnologyandEnvironment, TeUniversityoftheSouthPacifc,
Suva, Fiji
3
Department of Civil Engineering, Faculty of Engineering, Sri Lanka Institute of Information Technology, Malabe, Sri Lanka
4
Department of Civil Engineering and Construction, Faculty of Engineering and Design, tlantic Technological University,
Sligo, Ireland
Correspondence should be addressed to Upaka Rathnayake; upaka.r@sliit.lk
Received 1 July 2022; Revised 9 November 2022; Accepted 11 January 2023; Published 2 February 2023
Academic Editor: Mahmoud Nasr
Copyright © 2023 Kaamil Edward et al. Tis is an open access article distributed under the Creative Commons Attribution
License,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperly
cited.
Graphene, a 2D sp
2
hybridized carbon sheet consisting of a honeycomb network, is the building block of graphite. Since its
discovery in 2004, graphene’s exceptional electronic and mechanical properties have peaked interest in various applications.
However,theinabilitytomassproducehigh•qualitygrapheneafordablycurrentlylimitsthepracticalapplicationofthematerial.
Researchers are continuously working on advancing graphene synthesis methods to alleviate these limitations. Terefore, this
review looks at the overview of established graphene synthesis methods and characterization techniques, and then highlights an
in•depth review of graphene production through fash joule heating. Te environmental concerns related to graphene synthesis
are also presented in this review paper.
1.Introduction
Since graphene was frst isolated in 2004, research on pro•
duction methods and applications have increasingly pro•
gressed due to its unique properties which suggest the
imminenttransformationinthematerialsusedinelectronics,
composites,energy,andanticorrosivecoats.Withdemandfor
graphene and graphene•based materials growing (an esti•
mated USD 170 million in global markets by 2022), there is
a need to synthesize it at an industrial capacity. Existing
manufacturing methods are not fully capable of producing
reliable and cost•efective graphene to meet industrial ap•
plications; hence, the implementation of graphene has been
limited [1]. However, the waste can be converted into high•
quality turbostratic graphene using the fash joule heating
(FJH)process.TeFJHmethodshowstheimmensecapability
ofbeingascalableandcost•efectivesynthesisprocessbecause
of the compatibility of the process with various carbon
precursors without the need for pretreating with chemicals,
bufer gases, substrates, or washing of graphene.
Joule heating approach has been previously investigated
forthesynthesisofcarbonmaterialsandalloynanoparticles.
(i) A chemical vapor deposition system that uses Joule
heatingtoheatanickelflmonaSiO
2
/Sisubstrateto
900to1000
°
C(usingcurrentandvoltagerangewas
15–30A and 8–12V) followed by annealing in an
argon and hydrogen mixture at a fow rate of 50
sccm.Tesubstrateisthenexposedtomethaneat50
sccm for 20 to 60s. 20s of exposure results in the
formation of graphene with a resistance of 600 Ω/
square with a 93% transmittance [2].
(ii) A carbothermal shock process uses carbonized silk
fabric (CSF) loaded with a solution of transition
Hindawi
Applied and Environmental Soil Science
Volume 2023, Article ID 8475504, 23 pages
https://doi.org/10.1155/2023/8475504