CO
2
fluid inclusion barometry in mantle xenoliths from central Mexico: A
detailed record of magma ascent
Gilles Levresse
a,
⁎, Karina Elizabeth Cervantes-de la Cruz
a
, José Jorge Aranda-Gómez
a
,
María Guadalupe Dávalos-Elizondo
a
, Sergio Jiménez-Sandoval
b
,
Francisco Rodríguez-Melgarejo
b
, Leticia Araceli Alba-Aldave
c
a
CGEO-UNAM; Campus Juriquilla, Juriquilla, Querétaro 76320, Mexico
b
Centro de Investigación y de Estudios Avanzados del I.P.N., P.O. Box l 1-798, Querétaro 76001, Mexico
c
Instituto de Geología-UNAM; Distrito Federal, 04510, Mexico
abstract article info
Article history:
Received 23 April 2015
Accepted 18 November 2015
Available online 30 November 2015
Chemical equilibrium and CO
2
fluid inclusion barometry are complementary techniques, as they register differ-
ent geological processes. Chemical equilibrium barometry records the pressure at the site where the xenoliths
were incorporated into the transporting magma, but it is not a sensible technique to document magma ascent.
CO
2
fluid inclusion pore pressure in xenoliths does not register the P–T conditions in the source area, but it allows
illustrating a fairly detailed record of different geological processes that occurred during the magma transport to
the surface and as the eruption proceeded. Mantle xenoliths from Ventura–Espíritu Santo and Santo Domingo
volcanic fields contain dominant CO
2
pseudosecondary and secondary fluid inclusions trapped in cpx and ol.
Cpx chemical equilibrium pressures indicate a maximum pressure of 10 kbar for the source area. Pore pressures
obtained in CO
2
pseudosecondary and secondary fluid inclusions show a distribution with three maximum peaks
at ca. 8, 5–7, and less than 3 kbar. A comparison with geophysical models for the area where the xenoliths-
bearing volcanoes are located shows that the three peaks in the pore pressures correspond to three physico-
chemical transitions within the continental crust. Likewise, the pore pressure suggests that rapid magma ascent
is momentarily interrupted by these discontinuities, a fact that allows the formation of new fluid inclusions and
the re-equilibration of some of the inclusions already present in the primary minerals of the xenoliths.
© 2015 Elsevier B.V. All rights reserved.
Keywords:
Maar
Xenoliths
P–T evolution
Fluid inclusions barometry
Mexico
1. Introduction
Xenoliths included in the pyroclastic successions of mafic alkalic
maars are fairly well preserved rock samples from otherwise unreach-
able regions in the upper mantle and lower crust beneath the volcanoes
that brought them to the surface. The rapid ascent of intraplate mafic
magmas allows that the included mantle and crustal xenoliths arrive
to the surface with minimum mineralogical changes associated with
re-equilibration and/or serpentinization (e.g. Spera, 1984; Luhr and
Aranda-Gómez, 1997; Peslier et al., 2015). However, these xenoliths
commonly display some changes, such as interstitial glass or “spongy”
border zones in pyroxenes, induced by localized partial melting
produced by decompression and/or by reaction of the xenoliths with
the host magma. These secondary features overprinted on the meta-
morphic mineral paragenesis and/or textures suggest a more complex
ascent history (Nielson-Pike and Schwarzman, 1976). Putirka (2008)
inferred various pressures recorded in the Hawaiian lavas with the
pyroxene + liquid equilibrium methodology. The author interprets
the different pressures obtained as the record of magma ascent from
the Moho depth and its transit through the plastic flow to brittle
faulting transition (Rutter, 1986) in the middle crust, which is
influenced by changes of the mechanical properties of the rocks
where the volcanic conduit crosses.
Fluid inclusions provide a large amount of valuable information on
the origin and forming condition of host minerals and rocks where
they occur. Most mantle-derived minerals contain CO
2
as a dominant
component in their fluid inclusions, although CO
2
is not the only com-
ponent (e.g. Roedder, 1965, 1983; Andersen and Neumann, 2001;
Hidas et al., 2010; Berkesi et al., 2012; Frezzotti et al., 2012a; Frezzotti
and Touret, 2014). The density of CO
2
in a CO
2
fluid inclusion in a mantle
mineral is a well-proven geobaromter. Estimation of depth from which
the mantle rocks are carried up by ascending magma provides impor-
tant information about the chemical–physical properties of the mantle
(Longpré et al., 2014). Fluid inclusions found in peridotite xenoliths
can be used to infer key information regarding the depth of xenolith en-
trapment in ascending host magma and about the nature of the metaso-
matic agents that may have modified the original lithology in the source
area (Peccerillo et al., 2006). To understand the origin and evolution of
the xenoliths and the ascent history of the magmas, only unmodified
Journal of Volcanology and Geothermal Research 310 (2016) 72–88
⁎ Corresponding author.
E-mail address: glevresse@geociencias.unam.mx (G. Levresse).
http://dx.doi.org/10.1016/j.jvolgeores.2015.11.012
0377-0273/© 2015 Elsevier B.V. All rights reserved.
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