Journal of Civil Engineering Research 2015, 5(4A): 11-16
DOI: 10.5923/c.jce.201501.03
The Effects of Nano Silica Particles on the
Physical Properties and Storage Stability of
Polymer-Modified Bitumen
Dhawo Ibrahim Alhamali
1,*
, Nur Izzi Md. Yusoff
1
, Jiantao Wu
2
, Quan Liu
2
, Shaban Ismael Albrka
1
1
Dept. of Civil and Structural Engineering, Universiti Kebangsaan Malaysia, Malaysia
2
College of Civil and Transportation Engineering, Hohai Universiti, China
Abstract This study was conducted to investigate the physical and morphological properties and storage stability of
polymer modified bitumen’s (PMB) mixed with nanosilica (NS). Polymer modified bitumen, PG-76 and NS were mixed with
concentration of bitumen’s weight at 0, 2, 4 and 6%. Throughout the process, the binders were regulated at 163°C and
blended using a shear rate of 3000 rpm for 1 hour. Microscopic examinations of the bituminous binders were then carried out
using a scanning electron microscopy (SEM); the SEM images show that the NS particles disperse well in the bituminous
binder matrix. The NS’ effect on the physical properties and an additional NS in the PMB identified to some extent reduced
viscosity and ductility at 2 and 4% of NS, at 6% were stable to increase. Additionally, the NS-PMBs binders softening point
increased and penetration decreased. Furthermore, NS-PMBs binders’ storage stability depended mainly on NS content and
the storage stability succeeded with NS at concentration 6% by weight of bituminous binder. As result, the nanosilica
particles are a good modifier in inhibiting oxidizing reactions in the bitumen binder.
Keywords Nano-polymer modified bitumen, Nano Silica Particles, Physical properties, Storage stability
1. Introduction
Bitumen is made up of complex composition of chemical
that displays viscous and elastic properties equally which
rely comprehensively on time and temperature [1].
Researchers and engineers have tried to utilize different
types of modifiers to amend and better how bitumen
materials perform, together with styrene butadiene styrene
(SBS) [2]. Many researchers have revealed how
polymer-modified bitumens better the possible deficiencies
with the asphalt mixture pavements overall performance [3].
The styrenic block copolymers (e.g. styrene–butadiene–
styrene, SBS) seem to have the highest potential to benefit
bitumen modification [4]. And it was known that the
addition of SBS can improve conventional bitumen
compositions physical and mechanical properties [5].
Nevertheless, the stability of the SBS-modified bitumen
storage is generally poor when temperatures are raised due
to the SBS and bitumen weak compatibility. Several
methods have been established to prepare stable practical
storage SBS-modified bitumen. The succeeding growth
of polymer nanocomposites has caused a great interest in
* Corresponding author:
Dhawo_ibrahim@yahoo.com (Dhawo Ibrahim Alhamali)
Published online at http://journal.sapub.org/jce
Copyright © 2015 Scientific & Academic Publishing. All Rights Reserved
academic and industrial communities. Essentially, polymer
nanocomposites are made up of a blend of one or more
polymers with various nanomaterials such as nanoclays,
carbon nanotubes, etc. [6].
The use of nanomaterial in asphalt pavement started
rather late. Nano-technology is utilized as a new material,
device and system at the molecular stage. Several
nano-materials which have been or have the possibility to
be utilized to modify bitumen, such as nano-clay,
nano-silica, nano-hydrated lime, nano-sized plastic powders,
or polymerised powders, nano-fibres, nano-tubes to name a
few [7].
Yao et al. [4] gauge the rheological properties and
bituminous binders which have been modified with nano
are blended with nanosilica chemical bonding. In this
research, adding nanosilica to the control bitumen at
contents 4% and 6% decided on the bituminous binders’
weight. The study showed that the antiaging property,
rutting and fatigue cracking nanosilica modified binders’
performance are improved, and nanosilica added in the
control asphalt mixture considerably betters in terms of
dynamic modulus, flow number, and resistant to rutting
(permanent deformation).
Nano-SiO2 powder and SBS probable benefits were
reported for the asphalt mixtures used on pavements. A
primary study was carried out to determine bituminous
binder and modifiers physical properties. The results of this