IEEE TRANSACTIONS ON MAGNETICS, VOL. 50, NO. 9, SEPTEMBER 2014 4800204
Study of Exchange Bias in All Ferromagnetic
Fe/Co Soft/Hard Bilayer
Harkirat Singh
1
, Ratnesh Gupta
2
, Tanmoy Chakraborty
1
, Ajay Gupta
3
, and Chiranjib Mitra
1
1
Indian Institute of Science Education and Research Kolkata, Mohanpur 741252, India
2
School of Instrumentation, Devi Ahilya Vishwavidyalaya, Indore 452001, India
3
UGC DAE CSR, Indore Centre, Indore 452001, India
We report the unusual and exotic phenomenon of positive exchange bias observed in all ferromagnetic layered soft/hard Fe/Co
spring magnet systems. Interestingly, the results are well reproducible both at low (5 K) and room temperatures (300 K). The effect
of applied magnetic pinning field of 7 and -5 T reveals a noticeable shift of magnetic hysteresis loops along the field direction. We
argue that the reason behind observed positive exchange bias is the establishment of antiferromagnetic (AFM) exchange coupling
at the interface as a result of intermixing of Fe into the Co layer. The collective coupling of this intermix layers is AFM which
facilitates positive shift of magnetic hysteresis loop.
Index Terms— Antiferromagnetic (AFM) materials, magnetic films, magnetization, sputtering.
I. I NTRODUCTION
E
XCHANGE bias (EB) is an interesting phenomenon
pertaining to its immense technological applications in
data storage industries [1]. It has been studied extensively in
ferromagnetic (FM)/antiferromagnetic (AFM) bilayers, when
one field cools the system through the Neèl temperature of
AFM phase [2]. Owing to FM/AFM interfacial exchange
interaction, a shift in magnetization loop is usually observed.
Immense efforts have been put together to understand the
underlying physics of EB, yet an appropriate theoretical model
is still lacking. It has been predicted that the uncompensated
AFM spins at the interface of AFM–FM system might be
contributing to EB through short-range exchange coupling
between the AFM–FM bilayer [3]. The EB has been studied
thoroughly in various systems (in-homogeneous materials [4],
small systems, and thin films [5]) considering FM and AFM as
two magnetic materials. However, recent reports have explored
EB in other magnetic systems, namely phase separated man-
ganites (bulk) [6], ferrimagnet (FI)–FM, FI–FI [7], nanostruc-
tures [8], and AFM–dilute AFM [9]. These experimental inves-
tigations have reignited the interest of researchers to investi-
gate further such an old and interesting scientific phenomenon.
Depending on the nature of exchange coupling at the inter-
face (FM or AFM), it was proposed that the shift in magnetic
hysteresis loop can be negative or positive [3], [10]. The EB
shift is usually defined as H
E
= ( H
C 1
+ H
C 2
)/2, where H
C 1
and H
C 2
are the coercive fields on the left and right side
of the magnetic hysteresis loop, respectively. In comparison
with usual negative EB, positive EB (PEB) is quite rare and
treated as an exotic phenomenon. The reason behind the more
Manuscript received October 18, 2013; revised March 12, 2014 and
March 19, 2014; accepted March 21, 2014. Date of publication March 27,
2014; date of current version September 9, 2014. Corresponding author:
C. Mitra (e-mail: chiranjib@iiserkol.ac.in).
Color versions of one or more of the figures in this paper are available
online at http://ieeexplore.ieee.org.
Digital Object Identifier 10.1109/TMAG.2014.2313590
interesting PEB is believed to be the establishment of AFM
interfacial coupling. Hence, observation of PEB in an all
FM bilayer system has been considered to be unique and
intriguing [11]. Ke et al. [11] have demonstrated that AFM
exchange coupling that give rise to PEB, can exist between
two FM layers. In contrast to conventionally used AFM layers
to observe EB, an FM pinning layer provides a unique advan-
tage of experimental access to change in their magnetization
states [12]. The prototypical properties possessed by these FM
bilayer systems are interesting for the fundamental understand-
ing of EB. Experimentally, these systems are far more ideal to
study EB than the conventional FM–AFM systems owing to
the FM nature of the pinning layer [13]. Two FM layers, one
soft magnetic (SM) and another hard magnetic (HM) material
forms an exchange-spring magnet, where SM grains provide
enhanced magnetic moment and HM gives high anisotropy
and coercive field [14]–[16]. Exchange-spring magnets have
attracted considerable attention because of their application as
permanent magnets [17]. Presence of direct exchange coupling
between soft and hard FM phases causes single phase-like
magnetization reversal [18]. Goto et al. [14] have studied
the switching behavior of composite thin films where SM
and HM layers are ferromagnetically coupled. They assumed
that HM layer is rigid while SM layer has no anisotropy.
Study of EB in exchange-spring magnet systems could be of
great importance from the perspective of exploring interesting
aspects of interfacial physics [18], [19].
In this paper, we have demonstrated PEB in exchange-
coupled soft/hard Fe/Co bilayer. The bilayer of Fe and Co
form a suitable exchange coupled spring magnet, where Co,
being highly coercive, is chosen as HM and Fe, with less
anisotropy, play the role of SM. Magnetization curves were
obtained with the applied field direction along the plane of
thin film, which is the same as that of the deposition field
axis. A positive exchange bias was observed at all measured
temperatures. The effect of large applied magnetic pinning
field (+7 and -5 T) results in complete shift of magnetic
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