Vol.:(0123456789) 1 3 Rendiconti Lincei. Scienze Fisiche e Naturali https://doi.org/10.1007/s12210-018-0732-5 THE QUANTUM WORLD OF MOLECULES Nitronyl nitroxide radicals at the interface: a hybrid architecture for spintronics Lorenzo Poggini 1  · Giuseppe Cucinotta 1  · Lorenzo Sorace 1  · Andrea Caneschi 2  · Dante Gatteschi 1  · Roberta Sessoli 1  · Matteo Mannini 1 Received: 10 May 2018 / Accepted: 25 July 2018 © Accademia Nazionale dei Lincei 2018 Abstract Cross-fertilization between molecular magnetism and organic spintronics is leading to the development of concepts based on the use of molecules as active elements to infuence spin-related transport processes. The research on hybrid devices, where the magnetic molecules in contact with the electrodes infuence the spin and charge injection and transport, is moving its frst steps but is expected to quickly expand the technological potential of molecular spintronics and quantum computing. New exciting possibilities, linked to the individual properties of these molecular units and to their interaction with novel substrates, are getting disclosed. The chemical functionalization of these molecules is the tool which allows to tune their electronic and magnetic properties and to directly create these hybrid architectures. However, the coupling of molecules with the spin transport phenomena is far from being trivial. First, the stability of molecules in the device environment must be tested and, subsequently, the organization of molecules in the desired architectures must be mastered permitting a careful control of the interactions between inorganic substrates and molecular layers. Here we summarize how this research activity can be developed in the case of one of the simplest magnetic molecules, an organic radical. We will start from an innocent surface, such as gold, to move then toward a real-device environment. We evidence how these eforts can result in a surface- specifc molecular-based method to infuence the spin injection and transport phenomena, paving the way for developing new devices in which a fne-tuning of magnetic features is required. Graphical abstract Keywords Organic radicals · Nitronyl nitroxide · Nanostructured layers · Molecular magnetism · Molecular spintronics * Matteo Mannini matteo.mannini@unif.it Extended author information available on the last page of the article