ISSN 1995-0780, Nanotechnologies in Russia, 2012, Vol. 7, Nos. 9–10, pp. 509–516. © Pleiades Publishing, Ltd., 2012.
Original Russian Text © A.A. Gusev, I.A. Fedorova, A.G. Tkachev, A.Yu. Godymchuk, D.V. Kuznetsov, I.A. Polyakova, 2012, published in Rossiiskie Nanotekhnologii, 2012, Vol. 7,
Nos. 9–10.
509
INTRODUCTION
Since the early 1990s, the development, manufac-
ture, and introduction of carbon nanostructured
materials have been the most rapidly growing branch
of nanotechnologies [1]. In particular, carbon nano-
tubes (CNTs) are promising for obtaining ultrastrong
threads and composite materials, transistors and fuel
cells, capsules for the storage of metals and gases,
high-selective molecular sieves, display devices, and
light-emitting diodes [2]. They are also used in target-
ing pharmaceuticals and the production of biomateri-
als and biosensors [3]. Therefore, the safety of this
class of nanomaterials in regards to labor and health
have come to the fore [4] and investigating the toxic
action of carbon nanomaterials (CNMs) is among the
most urgent tasks of toxicology and environmental
toxicology [5].
The number of publications on nanoparticle toxi-
cology has been exponentially growing within the last
six years [6, 7]. Because CNMs are produced in
greater amounts than any other nanomaterial, numer-
ous studies are focused on their toxic action, migra-
tion, and entry into the environment.
Many authors demonstrate the high stability of
nanotubes in the environment. For example, CNTs
can form stable aerosols in disposal by incineration
[8]. They are also resistant to degradation in soil [9].
These are prerequisites for their migration to the
hydrosphere followed by absorption or adhesion by
living organisms.
After entry to the hydrosphere with sewage or pol-
luted air, engineered nanoparticles first enter aquatic
organisms: zoo- and phytoplankton, fishes, benthic
invertebrates, etc. These organisms are the bases of
food webs, which makes them the most probable site
for the primary accumulation of all fine abiogenic pol-
lutants, including nanoparticles [10].
Single- or multiwalled CNTs can enter the alimen-
tary tract of aquatic invertebrates and accumulate
there [11]. They cause disorders in hydrosphere inhab-
itants [12] and delay embryonic development [13].
Fullerene C60 adhesion to crustacean bodies (para-
sites Acartia tonsa) has been reported to disturb their
behavior and physiology [14].
The factors conjectured to determine the toxicity
of CNTs include heavy-metal penetration [15], the
mechanical breakdown of physical barriers in cells and
cell membranes (membrane stress) [16, 17], the cata-
lytic and inhibitory action of nanomaterials on bio-
chemical processes [17], and free radical formation
[9, 18, 19].
Little information on the cytogenetic action of
CNMs is available. An analysis of the mitotic index (MI),
chromosomal aberrations, micronuclei, and DNA
Acute Toxic and Cytogenetic Effects of Carbon Nanotubes
on Aquatic Organisms and Bacteria
A. A. Gusev
a
, I. A. Fedorova
b
, A. G. Tkachev
c
, A. Yu. Godymchuk
d
,
D. V. Kuznetsov
e
, and I. A. Polyakova
a
a
Derzhavin State University, Medical Institute, ul. Sovetskaya 93, Tambov, 392000 Russia
b
National Research Center Chernyshevskii State University, ul. Astrakhanskaya 83, Saratov, 410012 Russia
c
NanoTekhTsentr, ul. Sovetskaya 51, Tambov, 392000 Russia
d
Tomsk Polytechnic University, pr. Lenina 30, Tomsk, 634050 Russia
e
National University of Science and Technology “MISiS,” podr. 217, Leninskii pr. 4, Moscow, 119049 Russia
e-mail: nanosecurity@mail.ru
Received December 21, 2011; accepted May 16, 2012
Abstract—This paper summarizes a comprehensive study concerning the acute toxicity of a commercial car-
bon nanomaterial consisting mostly of carbon nanotubes to larvae of Chironomidae, crustaceans Ceriodaph-
nia affinis, algae Scenedesmus quadricauda, and bacteria Escherichia coli. It is shown that the nucleolar orga-
nizer region (NOR) index of polytene chromosomes in the salivary gland cells of midge larvae depends on the
duration of concentration and exposure. This fact is indicative of the switching on of cell adaptation pathways
in response to a xenobiotic stressor to restore cell homeostasis. The investigated nanomaterial is labeled as a
Class III environmentally hazardous material (moderately hazardous). Safe concentrations of the carbon
nanomaterial in aquatic media are less than 2 mg/l. It is concluded that larvae of Chironomidae are the most
resistant to the material of all test species, whereas Scenedesmus quadricauda and Escherichia coli are the most
sensitive.
DOI: 10.1134/S1995078012050060