American Journal of Engineering and Applied Sciences 7 (1): 66-76, 2014
ISSN: 1941-7020
© 2014 R.C. Walters et al., This open access article is distributed under a Creative Commons Attribution
(CC-BY) 3.0 license
doi:10.3844/ajeassp.2014.66.76 Published Online 7 (1) 2014 (http://www.thescipub.com/ajeas.toc)
Corresponding Author: Elham H. Fini, Department of Civil, Architectural and Environmental Engineering,
North Carolina A and T State University, 1601 E. Market Street, Greensboro, NC 27411,
USA Tel: (336) 285-3676 Fax: (336) 334-7126
66 Science Publications AJEAS
ENHANCING ASPHALT RHEOLOGICAL
BEHAVIOR AND AGING SUSCEPTIBILITY
USING BIO-CHAR AND NANO-CLAY
Renaldo C. Walters, Elham H. Fini and Taher Abu-Lebdeh
Department of Civil, Architectural and Environmental Engineering,
North Carolina A and T State University, Greensboro, NC 27411, USA
Received 2014-01-31; Revised 2014-02-13; Accepted 2014-03-24
ABSTRACT
The life expectancy of Asphalt Binder (AB) has been negatively impacted by the harsh bombardment of UV
rays. UV rays cause asphalt to oxidize faster, which results in deterioration of asphalt rheological
characteristics that can lead to pavement distresses. This study investigates the impact of bio-char and nano-
clay of asphalt rheological properties. Two nano scale materials were used for this study were nano-clay and
bio-char. Nano-clay (Cloisite 30B) is a naturally occurring inorganic mineral. Bio-char is the waste product
from bio-binder production. Bio-binder is produced from swine manure using a thermochemical conversion
process. This process is then followed by a filtration procedure where the bio-char is produced. Chemical and
physical properties of bio-char showed a significant presence of carbon which could in turn enhance asphalt
flow properties and reduce the rate of asphalt oxidation. In this study several mixtures are designed and
evaluated using Rotational Viscometer testing (RV) and X-Ray Diffraction (XRD). Nano-clay is blended at 2
and 4% by weight, with and without bio-binder (5% by weight of dry mass). Bio-char is grinded to nano scale
and added to the virgin asphalt binder (PG 64-22) at 2, 5 and 10% by weight. The study results showed that
introduction of nano-clay could be effective in reducing temperature susceptibility of asphalt binder.
Keywords: Oxidation, Nano-Particle, Bio-Modification, Rheological Properties, Aging Susceptibility
1. INTRODUCTION
The physiochemical mechanisms of asphalt oxidative
aging and changes in the performance-related properties of
asphalt have been the subject of numerous research
investigations and much speculation for many decades. In
this study two nano materials: Nano-clay and bio-char are
blended separately with Asphalt Binder (AB) and Bio-
Modified Binder (BMB) to reduce enhance asphalt
properties and reduce oxidation aging. The selected AB
was PG 64-22, which is commonly used in North Carolina
and BMB was a bio-asphalt produced at NC A&T farm
mainly from swine manure (Fini et al., 2011a). Due to
increasing concerns about the service life of asphalt
binders, this study strives to decrease the rate of asphalt
oxidation, which is known as one of the main causes of
pavement distresses. This in turn will enhance rheological
behavior of asphalt and extend pavement service life by
reducing asphalt aging susceptibility.
Asphalt binders are most commonly characterized by
their physical properties. Asphalt binder’s
physiochemical properties determine how it will perform
as a constituent in Asphalt Concrete (AC) pavement.
Although asphalt binder viscosity grading is still
common, new binder tests and specifications have been
developed to more accurately characterize asphalt
binders for use in AC pavements (ASTM, 2013). These
tests and specifications are specifically designed to