DEVELOPMENT OF HPLC STABILITY DEMONSTRATING METHODOLOGY FOR QUANTIFYING
AZELNIDIPINE AND TELMISARTAN IN TABLETS AND BULK TYPES: VALIDATION FOLLOWING
ICH DIRECTIVES
Original Article
KRISHNAPHANISRI PONNEKANTI
1*
, K. SUNITHA
1
1
Department of Pharmacy, GITAM Institute of Pharmacy, GITAM Deemed to be University, Visakhapatnam, India 530045
Email: krishnaphanisri@gmail.com
Received: 18 May 2021, Revised and Accepted: 26 Jun 2021
ABSTRACT
Objective: Azelnidipine (AZEL) and Telmisartan (TELM) combination is referred to the sufferers of hypertension. No analytical process has yet
been mentioned for the TELM and AZEL combination analysis. We, therefore, have designed for its first time stability demonstrating methodology
based on HPLC for analysing TELM and AZEL in the tablets and bulk.
Methods: The assay of TELM and AZEL was get done on a 250 mm length C18 column (Supelco, 4.6 mm inner diameter, 5.0 μm particle size), and
utilized 0.1M Na2SO4 (pH 3.6) and acetonitrile (55% volume: 45% volume) as the mobile solvents phase, at a stream rate 1.0 ml/min. HPLC
recognition of TELM and AZEL was taken by a photodiode array sensor set at 258 nm. For validation of the stability demonstrating methodology
proposed in terms of sensitivity, precision, specificity, linearity, device adequacy, robustness and accuracy, ICH directives were followed.
Results: Calibration curves of TELM and AZEL were generated in the array of 20-60 µg/ml and 4-12 µg/ml with recovery percentage ranges of
99.62%-101.05% and 97.76%-100.17%, and detection limits of 0.020 µg/ml and 0.009 µg/ml, respectively. TELM and AZEL stability was inspected
in the existence of acid, base, light, heat, and oxidation and it was realised to be more stable under oxidation degradation testing conditions
employed when compared to acid, alkaline, photo, and heat degradation testing conditions applied.
Conclusion: The observations demonstrated that the described HPLC stability demonstrating methodology was suitable for quantitating TELM and
AZEL combination in tablets and bulk.
Keywords: Azelnidipine, Telmisartan, Hypertension, Stability demonstrating, Analysis
© 2021 The Authors. Published by Innovare Academic Sciences Pvt Ltd. This is an open access article under the CC BY license (https://creativecommons.org/licenses/by/4.0/)
DOI: https://dx.doi.org/10.22159/ijap.2021v13i5.42099. Journal homepage: https://innovareacademics.in/journals/index.php/ijap
INTRODUCTION
Hypertension is the extremely avoidable contributing factor for
cardiovascular impairments namely coronary cardiac disease, heart
attack, heart stroke, atrial fibrillation, pulmonary artery disease and
myocardial infarction, progressive renal disease and cognitive decline
[1]. Hypertension is the foremost single contributor to the world’s
leading basis of demise and disability. In 2010 it is valued that 1.39
billion (31.1%) of adults globally be ill with hypertension. In middle
and small revenue nations (1.04 billion people and 31.5%), the
occurrence of hypertension among adults was elevated than in the
high revenue nations (349 million individuals and 28.5%) [2].
Azelnidipine (AZEL), structure in fig. 1, is a modern dihydropyridine
calcium passage antagonist that is particular for the L-kind calcium
passages and has received FDA authorization for therapy of the
hypertension clients [3]. Antihypertensive outcomes of AZEL are
equivalent to that of amlodipine [4]. AZEL is indeed increasingly
lipid-soluble and has greater selectivity for the vascular surface than
older generational calcium passage antagonists, and in animal
experiments treated with AZEL, blood flowing to the brain was
markedly enhanced [5].
Telmisartan (TELM), structure in fig. 1, is an angiotensin (II)
receptor blockade being used to alleviate minimal to severe
hypertension [6-8]. TELM is extremely selective for the type 1
angiotensin (II) receptors. TELM is an extra lipophilic angiotensin
(II) receptor blocker than utmost other angiotensin (II) receptor
inhibitors, which aids its oral uptake and tissue as well as cell
permeation [9]. TELM too has an impact on the peroxisome
proliferator triggered receptors, which are nuclear hormone
receptor superfamily ligand triggered transcription elements. TELM,
a drug that treats both diabetes and hypertension, may well be an
alternative therapy choice [10, 11].
The combination of TELM and AZEL is recommended for
hypertension sufferers. In hypertension sufferers, TELM and AZEL
combination drops blood pressure, enables blood to flow more
effectively to numerous tissues, allows the heart to operate more
effectively, and increases oxygen flow across the body, and thereby
reducing heart-associated chest pain [12].
Fig. 1: Azelnidipine (AZEL) and Telmisartan (TELM) structures
Stress tests must be implemented on a medication compound to
ascertain its basic stability properties, bestowing to the “ICH Q1A
(R2)” parent drug permanency evaluation recommendations [13].
Understanding how a drug substance's consistency varies with times
and the nature of deterioration products generated under different
International Journal of Applied Pharmaceutics
ISSN- 0975-7058 Vol 13, Issue 5, 2021