Journal of Building Engineering 34 (2021) 102055
Available online 2 December 2020
2352-7102/© 2020 Elsevier Ltd. All rights reserved.
Infuence of binary antifreeze admixtures on strength performance of
concrete under cold weather conditions
Jeeshan Khan
*
, Santha Kumar G.
CSIR-Central Building Research Institute, Roorkee, 247 667, India
A R T I C L E INFO
Keywords:
Cold weather exposures
Mortar
Concrete
Antifreeze admixtures
Freezing and water revitilization
ABSTRACT
The present research addresses the infuence of using binary antifreeze admixtures on the strength performance
of concrete under different curing exposures of cold weather conditions. A comparison with the strength per-
formance of controlled concrete under the curing exposures of cold weather conditions is also explored. Calcium
nitrate and sodium thiocyanate were the binary antifreeze admixtures used in the present study. Concrete
specimens were cured at different cold weather conditions such as, 1) freezing temperature of -5
◦
C and 10
◦
C,
2) freezing temperature of -5
◦
C and 10
◦
C along with water revitalization, 3) freezing and thawing cycles, 4)
freezing and thawing cycles along with water revitalization. The present study inferences that the synergetic use
of calcium nitrate and sodium thiocyanate have a great infuence on strength enhancement of concrete under the
infuence of various curing exposures of cold weather conditions that would be a constructive solution to pro-
mote the concrete applications in cold weather conditions.
1. Introduction
ACI 306 states cold weather when following climatic conditions exist
for the period of more than three consecutive days: the temperature
below 4
◦
C and air temperature drops below 10
◦
C for one-half of 24 h
[1]. The major drawbacks associated with the cold weather curing
exposure of concrete are prolonged setting time, early damage, slow
hydration, low strength gain and generation of thermal cracks etc [2,3].
During the exposure of fresh concrete under cold weather conditions,
the mixing water inside the concrete tends to become ice, affecting its
setting characteristics. It is because, the conversion of hydration product
from ettringite to monosulphate is predominantly affected [4,5]. During
the exposure of hardened concrete under cold weather conditions, the
water inside the concrete pores generally tends to become ice, causing
an increase the volume around 9% [6,7]. These effects exert pressure to
outward direction, creating high hydraulic pressure to the sorroundings.
Therefore, concrete is protected against freezing during plastic and
hardened states until achieving suffcient setting and hardening [8–10].
However, cold weather concrete attains substainially inferior perfor-
mance due to freezing of water during plastic and hardened states [11]
and therefore, it requires to be protected from freezing through: a) using
antifreeze admixtures, b) heating of raw materials and c) providing
insulation over concrete surface etc [12,13]. Among these methods, the
incoroporation of antifreeze admixtures in concrete under the curing
exposure of cold weather is economical and also feasible to applicable in
wide applications [14].
The use of antifreeze admixtures, such as, sodium chloride, sodium
nitrite, alcohol based compounds, carbamide, calcium chloride, calcium
nitrate and urea, had tendency to reduce the freezing point of the
aqueous solution, causing positive impact on performance enhancement
of concrete in cold weather conditions [7,13,15–18]. However, the
performance of cold weather concrete improved to full extent is still
questionable. Prolonged setting and slow hardening are the pressing
issues of cold weather concrete and therefore, the synergetic use of
setting and hardening admixtures are essential for developing the
desirable performance of cold weather concrete. Calcium nitrate is a
multifunctional admixture for concrete which can be used as setting
accelerator, antifreeze admixture and corrosion inhibitor etc [19]. So-
dium thiocyanate (NaSCN) is a sodium salt of thiocyanic acid (HSCN)
and used as hardeneing accelerator [20]. The synergetic use of setting
and hardening accelerators on the performance of cold weather concrete
is yet to be investigated. In addition to this, there have been insuffucient
knowledge on the performance of concrete exposed under various
curing exposures of cold weather conditions. Keeping consideration of
these concerns, the objective of this present paper is to investigate the
infuence of using binary antifreeze admixtures on the performance of
* Corresponding author.
E-mail addresses: jeeshank@cbri.res.in (J. Khan), santhakumar@cbri.res.in (S.K. G.).
Contents lists available at ScienceDirect
Journal of Building Engineering
journal homepage: http://www.elsevier.com/locate/jobe
https://doi.org/10.1016/j.jobe.2020.102055
Received 28 August 2020; Received in revised form 30 November 2020; Accepted 30 November 2020