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1801592 (1 of 9) ©
2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Electro-chemomechanical Contribution to Mechanical
Actuation in Gd-Doped Ceria Membranes
Eran Mishuk, Andrei Ushakov, Evgeniy Makagon, Sidney R. Cohen, Ellen Wachtel,
Tanmoy Paul, Yoed Tsur, Vladimir Ya. Shur, Andrei Kholkin,* and Igor Lubomirsky*
DOI: 10.1002/admi.201801592
δ - phase Bi
2
O
3
.
[8]
Thin films of CGO are
not difficult to deposit and, as has been
demonstrated, they can be incorporated
into Si-based devices using standard
micro-machining processes.
[9–12]
To
date, the electrostriction effect in CGO
has mainly been studied in the frame-
work of substrate supported films or
ceramics.
[6,7,13–15]
Previously, we have demonstrated the
feasibility of mechanical actuation with
CGO-based devices and have shown that
the choice of contact metal is critical for
functionality.
[12,14,16]
Of the electrodes
tested, titanium contacts were found to
display the lowest resistance.
[12,16]
How-
ever, the electromechanical response of
micro-electromechanical systems (MEMS)
based on CGO films was found to be com-
plex.
[12]
This complexity has two sources.
i) CGO is strongly anelastic.
[9,10,17,18]
The frequency range of the anelasticity
(<0.5 Hz) clearly overlaps the frequency
range within which nonclassical elec-
trostriction is observed,
[6,13,15]
making
precise identification of the nature of the
response difficult. ii) CGO is one of the best oxygen ion con-
ductors. Therefore, electrochemical oxygen exchange reactions
at the interface with a titanium electrode is possible even at
room temperature. These electrochemical reactions may induce
electro-chemomechanical (ECM) response, i.e., mechanical
deformation induced by electrochemically driven changes
in composition.
[19–21]
Therefore, ECM and electrostrictive
responses may superimpose.
Gd-doped ceria (CGO), one of the most extensively studied oxygen ion
conductors, is a low dielectric constant/low mechanical compliance material
exhibiting large nonclassical electrostriction. The electromechanical response
of the micro-electromechanical devices with CGO films as an active material
described previously can not be attributed exclusively to electrostriction. Here
it is shown that, below 1 Hz, in addition to electrostriction (second-harmonic
response), there is a strong contribution of the electro-chemomechanical
effect (ECM, first harmonic response). ECM is the change in mechanical
dimensions of ionic and mixed ionic-electronic conductors as a result of a
change in chemical composition induced by an electric field. In batteries,
the presence of ECM is highly detrimental. In ceria at room temperature, it
was considered to be negligible because of slow oxygen diffusion. This work
demonstrates ECM actuation at ambient temperature and moderate electric
field (<5 V μm
-1
). ECM-induced strain is attributed to reversible oxidation/
reduction of TiO
2
layers at the Ti-CGO interface. At 25 °C, the ECM bending
strain is 1.2 × 10
-6
, increasing exponentially with temperature. These data
suggest that with a proper choice of materials, ECM-type response can be a
viable mechanism for mechanical actuation at ambient and also at slightly
elevated temperatures.
E. Mishuk, E. Makagon, Dr. E. Wachtel, Prof. I. Lubomirsky
Department of Materials and Interfaces
Weizmann Institute of Science
Herzl St 234, Rehovot 7610001, Israel
E-mail: Igor.Lubomirsky@weizmann.ac.il
A. Ushakov, Prof. V. Ya. Shur, Prof. A. Kholkin
School of Natural Sciences and Mathematics
Ural Federal University
Lenin Ave. 51, Ekaterinburg 620000, Russia
E-mail: kholkin@ua.pt
Electro-Chemomechanical Actuation
1. Introduction
Gd-doped ceria (CGO) is one of the most extensively studied
ionic conductors, finding application in a variety of fields ranging
from fuel cells to memristors.
[1–4]
Recently, CGO was reported
to exhibit large non-classical (non-Newnham) electrostric-
tion.
[5–7]
This report was followed by the demonstration of
non-classical electrostriction in ceramics of (Nb, Y)-stabilized
Dr. S. R. Cohen
Department of Chemical Research Support
Weizmann Institute of Science
Herzl St 234, Rehovot 7610001, Israel
Dr. T. Paul, Prof Y. Tsur
Department of Chemical Engineering and the Grand Technion Energy
Program Technion-Israel Institute of Technology
Haifa 3200003, Israel
Prof. A. Kholkin
Department of Physics and CICECO-Aveiro Institute of Materials
University of Aveiro
3810-193 Aveiro, Portugal
The ORCID identification number(s) for the author(s) of this article
can be found under https://doi.org/10.1002/admi.201801592.
Adv. Mater. Interfaces 2019, 1801592