Available online at www.sciencedirect.com
ScienceDirect
Materials Today: Proceedings 4 (2017) 5651–5656 www.materialstoday.com/proceedings
2214-7853 © 2017 Elsevier Ltd. All rights reserved.
Selection and Peer-review under responsibility of INTERNATIONAL CONFERENCE ON MULTIFUNCTIONAL MATERIALS
FOR DEVICE APPLICATIONS(ICMDA-2016).
ICMDA 2016
CFO-Graphene nano composite for High Performance
Electrode Material
Sweety Supriya*, Sunil Kumar and Manoranjan Kar
Department of physics, Indian Insitute of technology Patna, Bihta-801103, Patna, India
Abstract
CoFe
2
O
4
-graphene nanocomposite with different graphene content (5, 10 and 15 wt%) were synthesized by the high
energy planetary Ball mill method using zirconium coated steel balls with a speed of 300 rpm for 24 hours. The structural
properties and molecular vibrations or rotations of the material were studied by the XRD and Raman spectroscopy respectively.
The electrical impedance (Zˈ) characterization reveals the increase in ac conductivity (σ
ac
) with the increase in graphene
percentage in the composite as compared to pure cobalt ferrite. The conducting nature of graphene is also being reflected by the
Nyquist plot. It is very interesting to note that the combination of CoFe
2
O
4
nanoparticles with graphene results in a dramatic
conversion of the inactive CoFe
2
O
4
into a highly conductive composite, which is suited as electrode material in energy storage
devices (supercapacitors, batteries, fuel cells and solar cells). The significant enhancement in conductivity under the applied
electric field of 2 V (peak to peak) and frequency range 1 Hz to 1 MHz has been observed at room temperature due to addition of
graphene in the CoFe
2
O
4
.
© 2017 Elsevier Ltd. All rights reserved.
Selection and Peer-review under responsibility of INTERNATIONAL CONFERENCE ON MULTIFUNCTIONAL
MATERIALS FOR DEVICE APPLICATIONS(ICMDA-2016).
Keywords: ac conductivity; Ball millin; Cobalt ferrite; Impedance; XRD.
Corresponding author
Email address: sweety@iitp.ac.in