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Research
Effect of Tungsten Content on Corrosion Resistance and Hardness of
Aluminum by Electro-less Coating
Muhammad Azeem ullah
1
, Salah Ud Din
1
, Ayesha Azeem
1
, Faisal Nazeer
2
, Abdul Malik
2
,
Muhammad Nouman Khan
3
, Muhammad Sajid
4*
1
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering,
Zhejiang University, Hangzhou 310027, People’s Republic of China
2
School of Materials Science and Engineering, Beijing Institute of Technology,Beijing
100081, China
3
School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China.
4
Beijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and
Green Applications, School of Materials, Beijing Institute of Technology, Beijing, China
*
Corresponding author
Accepted:12 August, 2019 ;Online: 19 August, 2019
DOI : https://doi.org/10.5281/zenodo.3371786
Introduction:
Abstract:Nickle-Tungsten-Phosphorous (Ni-W-P) alloy coating was prepared by electro-
less nickel plating on pure aluminum sheet. For activation of aluminum surface, pickling
and zinc immersion was carried out. Furthermore, reinforcement and reduction of
corrosion potential, copper electroplating was inspected before deposition for better
adherence. In this present research work focus on the variation of tungsten content in
chemical plating bath for constant plating time. Scanning Electron Microscopy (SEM) was
used to observe the surface morphology of the samples. Energy Dispersive Spectroscopy
(EDS) was used to determine the coating composition and thickness of the coating catalyst.
Behavior of hardness was measured by Vickers hardness tester techniques while its
porosity have been observed by stereoscope. The medium used for corrosion resistance
testing was 0.9% sodium chloride (NaCl) with hydrochloric acid (HCl) giving 4-5 pH. The
predominant phase in the coating was nickel along with phosphides of nickel and nodules
of tungsten content. Coating showed higher hardness and good corrosion resistance as
compared to substrate. With increase in tungsten content, hardness increased and
spherical size was decreased. Hence, uniform and thick coating was obtained.
Keywords : Aluminum surface;Corrosion potential;Tungsten; Electroplating;Hardness