Case study
Development of unfired earthen building materials using
muscovite rich soils and alkali activators
Emeso Beckley Ojo
a,
*, Kabiru Mustapha
b
, Ronaldo S. Teixeira
c
,
Holmer Savastano Jr
c
a
Department of Materials Science and Engineering, African University of Science and Technology, Nigeria
b
Department of Materials Science and Engineering, Kwara State University, Malete, Nigeria
c
Department of Biosystems Engineering, University of Sao Paulo, Pirassununga, Sao Paulo, Brazil
A R T I C L E I N F O
Article history:
Received 26 February 2019
Received in revised form 10 June 2019
Accepted 14 June 2019
Keywords:
Unfired earth
Building materials
Muscovite
Compressive strength
Alkali activators
A B S T R A C T
Most studies have focused on the alkali activation of thermally activated kaolinitic clays for
the production of innovative building materials. Whilst the widespread use of these
minerals may be hindered due to geographical availability; a combination of thermal
activation and alkali activator solutions yields a material with high embodied energy with
implications on eco-friendliness. This study presents an eco-friendly approach for the
development of a low environmental impact building material using a low molarity alkali
activator solution for the stabilisation of uncalcined muscovite rich soil. Influence of curing
conditions on the physical, mechanical, microstructural and mineralogical properties were
evaluated. Results show that alkali activation of uncalcined muscovite in the soil
significantly improved the physical and mechanical properties of extruded earthen
materials. Samples tested yielded compressive strength values between 9–11 MPa for
varying curing regimes. The binding was mainly attributed to the formation of amorphous
sodium aluminosilicate gels as a result of the partial dissolution of muscovite. These results
show that low environmental impact building materials may be developed with uncalcined
muscovite rich soils in developing regions around the world where these minerals are
predominant for the provision of sustainable low-cost housing solutions.
© 2019 The Authors. Published by Elsevier Ltd. This is an open access article under the CC
BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
1. Introduction
Owing to environmental challenges associated with the production of cement, significant research has focused on alkali
activated materials as alternative binders in construction materials [1,2]. Presently, extensive studies have demonstrated the
improved properties of alkali activated aluminosilicates over conventional Portland cement in concrete [3–5]. However, very
little work has been conducted to harness this technology for the development of earthen construction building materials. In
a practical sense, 65% of the earth crust comprises of natural aluminosilicates and this triggers the interest to determine if
alkali activation can be harnessed for the production of building materials from soils containing these minerals. Such
information will enhance the adoption and commercialisation of a new promising technology for the development of
construction materials. In theory, any material composed of silica and aluminium can be alkali activated. This has been
* Corresponding author.
E-mail addresses: eojo@aust.edu.ng (E.B. Ojo), kabiru.mustapha@kwasu.edu.ng (K. Mustapha), ronaldost@usp.br (R.S. Teixeira), holmersj@usp.br
(H. Savastano).
https://doi.org/10.1016/j.cscm.2019.e00262
2214-5095/© 2019 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/
licenses/by-nc-nd/4.0/).
Case Studies in Construction Materials 11 (2019) e00262
Contents lists available at ScienceDirect
Case Studies in Construction Materials
journal homepa ge: www.elsevier.com/locate/cscm