Citation: Bunge, L.; Silva, H.G.; Cruz,
P.L.; Iten, M. Testing of a Low-Cost
Dry Cell Prototype for Oxyhydrogen
Production. Designs 2022, 6, 79.
https://doi.org/10.3390/
designs6050079
Academic Editor: Quanqing Yu
Received: 18 July 2022
Accepted: 1 September 2022
Published: 7 September 2022
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Article
Testing of a Low-Cost Dry Cell Prototype
for Oxyhydrogen Production
Lisa Bunge
1
, Hugo G. Silva
2,3,
* , Pedro L. Cruz
4
and Muriel Iten
4
1
Cátedra de Energias Renováveis, Departamento de Eng. Mecatrónica, Universidade de Évora,
Rua Romão Ramalho 59, 7000-671 Évora, Portugal
2
Laboratório Associado de Energia, Transporte e Aeronáutica (LAETA), Departamento de Física, ECT,
Universidade de Évora, Rua Romão Ramalho 59, 7000-671 Évora, Portugal
3
INEGI Alentejo, Universidade de Évora, Largo dos Colegiais 2, 7000-803 Évora, Portugal
4
Low Carbon & Resource Efficiency, R & Di, Instituto de Soldadura e Qualidade, 4415-491 Grijó, Portugal
* Correspondence: hgsilva@uevora.pt; Tel.: +351-967-480-736
Abstract: This work aims to study the production of oxyhydrogen gas by a small low-cost prototype
consisting of six dry cells. Firstly, a molecular composition study of the gas was carried out, presenting
concentrations of 67% H
2
and 28% O
2
. The deviation from the stoichiometric yield is discussed to
be caused by water vapor production and/or oxygen dissolution in the liquid phase. Secondly, an
efficiency study was done, considering the ratio between the reversible voltage of an electrolytic cell
and the voltage applied to the dry cell by an external power source. Different working conditions
(electrolyte concentration, 3% (w/w) of KHO and 20% (w/w) of KHO) have been tested to analyze their
effect on the efficiency of the system. The results show that a lower electrolyte concentration increases
the applied cell voltage, and so the necessary power input for gas production to occur, resulting
in lower cell efficiency. Overall, the efficiencies are below 69.8 ± 0.6% for the studied electrolyte
concentrations and approach approximately the same value around 50% for higher powers.
Keywords: oxyhydrogen production; low-cost prototype; oxyhydrogen molecular composition; dry
cell efficiency
1. Introduction
Molecular hydrogen (H
2
) can be used as fuel for energy production and is considered
a secondary energy vector, since it does not exist in its pure form in nature. Hydrogen
can be obtained through various processes and from various sources, including through
the reformation of natural gas or biofuels; gasification of biomass and coal; electrolysis
of water or water vapor at high temperatures; thermochemical cycles; and photocatalytic
processes [1].
Hydrolysis is any chemical reaction in which water molecules break down one or more
of their chemical bonds. Electrolysis, in turn, consists of separating water into hydrogen
(H
2
) and oxygen (O
2
) using electrical energy [2], and occurs in electrolytic cells. This
process has an efficiency as high as 85%, however, the amount of electricity required makes
the overall process inefficient and often expensive [1].
Electrolysis is commonly made with the use of wet cells, which have two electrodes,
an anode, and a cathode, made from some inert metals, such as platinum and stainless steel,
or graphite. The electrodes are immersed in a water solution with an acid or a base, forming
an electrolyte, in order to increase the electrical conductivity of the solution. This aims to
reduce the enormous amount of energy required to perform the electrolysis of pure water,
since it is not a good electrical conductor [2]. The electrolyte, when dissolved in water,
results in a solution capable of conducting electricity. The electrolyte dissociates into cations
and anions, with cations attracted by the negative pole and anions by the positive pole of the
electrolytic cell. This allows the continuous flow of electricity, increasing the conductivity of
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