1 Supporting Information An Efficient Synthesis of Polysubstituted Pyrroles via Copper-Catalyzed Coupling of Oxime Acetates with Dialkyl Acetylenedicarboxylates under Aerobic Conditions Xiaodong Tang, Liangbin Huang, Chaorong Qi, Wanqing Wu, Huanfeng Jiang* School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China E-mail: jianghf@scut.edu.cn; Fax and Tel.: (+86) 20-87112906 Table of Contents General Information........................................................................................................................[2] Typical Procedure for the Preparation of Oxime Acetates………………………………………..[2] General Procedure for the Synthesis of Pyrroles …………………................................................[2] General Procedure for 4a, 4l ………………….............................................................................[2] Experimental procedures and characterization data for products 3a-3w, 4a, 4l..................[3] References……………………………………………………………………………….……....[10] NMR Spectra for Compounds 3a-3w, 4a, 4l………………………………………...…….……[11] Electronic Supplementary Material (ESI) for Chemical Communications This journal is © The Royal Society of Chemistry 2013