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Inorganic Chemistry Communications
journal homepage: www.elsevier.com/locate/inoche
Short communication
MoS
2
/CdS/TiO
2
ternary composite incorporated into carbon nanofbers for
the removal of organic pollutants from water
Bishweshwar Pant
a
, Mira Park
b,
⁎
, Soo-Jin Park
a,
⁎
a
Department of Chemistry, Inha University, 100 Inharo, Incheon 402-751, South Korea
b
Department of Bioenvironmental Chemistry, College of Agriculture & Life Science, Chonbuk National University, Jeonju 561-756, South Korea
GRAPHICALABSTRACT
ARTICLEINFO
Keywords:
Electrospinning
MoS
2
/CdS/TiO
2
/carbon
Nanocomposite
Photocatalysis
Wastewater treatment
ABSTRACT
MoS
2
/CdS/TiO
2
nanocomposites embedded on carbon nanofbers were synthesized via electrospinning method
followed by calcination under an inert atmosphere. The photocatalytic property of the as-synthesized nano-
composite was evaluated for the removal of methylene blue (MB). The obtained results showed that the pho-
tocatalytic efciency and stability of the composite nanostructures were highly enhanced as compared to the
pristine TiO
2
nanofbers. This work demonstrates the efective absorption capacity of carbon nanofber along
with the synergistic efect ofMoS
2
and CdS in which it proves to be a good choice for improving the utilization of
visible light activity of TiO
2
-based materials.
In recent years, semiconductor-based photocatalysis is of growing
interest in tackling the global energy and environmental crisis.
However, yet, the development of efcient, sustainable, inexpensive,
and environmentally-friendly photocatalysts remains a signifcant
challenge. Among the semiconductor metal oxides, titanium dioxide
(TiO
2
) has been extensively researched for environmental purifca-
tion applications and in water splitting for hydrogen generation
[1–4]. Although TiO
2
has a strong oxidation strength and high che-
mical stability, due to its wide band gap (3.2 eV) it is only active in
the UV light region of the solar spectrum, which accounts less than
5% of the total incident solar light [2,5]. Therefore, for the efective
use of TiO
2
, conspicuous eforts have been made to extend its re-
sponse spectrum towards the visible spectral region. Diferent stra-
tegies such as sensitizing with narrow-band-gap semiconductors or
forming new donor states below the conduction band of TiO
2
by the
incorporation of metal or non-metal elements into its crystal matrix
have been carried out in order to achieve enhanced light harvesting
ability under solar irradiation [6–8]. Among the various attempts to
enhance the visible light activity of TiO
2
, sensitization of TiO
2
with
CdS has been proven to be an excellent strategy for achieving high
https://doi.org/10.1016/j.inoche.2019.02.022
Received 10 December 2018; Received in revised form 11 February 2019; Accepted 15 February 2019
⁎
Corresponding authors.
E-mail addresses: wonderfulmira@jbnu.ac.kr (M. Park), sjpark@inha.ac.kr (S.-J. Park).
Inorganic Chemistry Communications 102 (2019) 113–119
Available online 16 February 2019
1387-7003/ © 2019 Published by Elsevier B.V.
T