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DOI: 10.1002/prep.201800178
Parameters of Aluminum Nanopowders Activity after
Long-Term Storage in an Airtight Container
Alexander Ilyin,
[a]
Dmitriy Tikhonov,
[a]
and Andrei Mostovshchikov*
[a]
Abstract: The work has established the change in the activ-
ity parameters of aluminum nanopowders produced by
electric explosion of a wire during their storage in an air-
tight container. The change in the characteristics of the
nanopowders using four activity parameters was measured
by benchmarking their activity after the production, passi-
vation and keeping for 10–20 days and after their storage
for 16 years. It was also established that after long-term
storage, the temperature of oxidation initiation for the
nanopowders in air has increased; the increment of mass
during oxidation at up to 800 8C for all specimens has in-
creased, while the content of metallic aluminum has de-
creased. The electrical double layer on the surface of alumi-
num nanoparticles during storing even in an airtight
container changes with time and does not provide the pro-
tective function. In this connection, the future application
of aluminum nanopowders in high-energy materials is not
feasible without solving the problem of their stability. Ac-
cording to the results, electric-explosion aluminum nano-
powder is an unstable aluminum-air system even in an air-
tight container.
Keywords: electric explosion of wire · aluminum nanopowder · chemical activity parameters · storage · airtight container
1 Introduction
One of the primary problems of practical application of alu-
minum nanopowders is conservation of metallic aluminum
and its reactivity [1–4]. Therewith, the production of alumi-
num nanopowder that is stable in air requires partial oxida-
tion combined with a reduction of aluminum content at
least down to 92–93 mas. %. The replacement of conven-
tional aluminum powders in pyrotechnical compositions
and rocket fuels by aluminum nanopowders with low con-
tent of metallic aluminum for the sake of improved per-
formance is not evident [5–7].
Any nanopowders are unstable or meta-stable solid
body-gas systems. As compared to compounds with low
dispersity, metallic nanopowders have prominent reactivity
[8–10] and interact with their environment [11,12]. The
main oxidizer of metallic nanopowders are protons that
form after dissociation of water molecules on the surface of
nanoparticles [13, 14]. The structure of metallic nano-
particles [15] formed after passivation in air is peculiar for
an electrical double layer (EDL): adsorbed water molecules
dissociate into protons that diffuse into a nanoparticle and
hydroxide ions that stabilize on the surface. The latter
chemically bond with the nanoparticle surface, while pro-
tons oxidize the metal yielding atoms and molecules of hy-
drogen [13]. For a number of metals (aluminum, titanium,
zirconium and hafnium), protons form respective hydrides
[13]. With the decrease in the diameter of metal particles,
the state of atoms – initially on the surface, and from the
diameter of 30 Æ 10 nm, inside the particles as well – be-
comes unstable [14]. The formation and nature of pro-
tective films on the surface of aluminum particles depends
on their diameter (surface curvature). When the diameter di-
minishes down to 1 mm, the diffusion mechanism of pro-
tective film formation persists, which thickness varies from
20 to 40 mm. For the aluminum particles with the diameter
less than 100 nm, due to the change in atom state on the
surface, the nature of the protective film also changes. The
process of aluminum oxidation in nanostate decelerates af-
ter the formation of electrical double layer having pseudo-
capacitance with internal positively charged layer [13, 15].
The stability of the double layer determines the stability of
aluminum nanopowders during storage. Indirect evidence
of the electrical double layer is the much lesser thickness of
the protective layer of 2–10 nm [13, 15]: with a decrease in
the diameter of aluminum nanoparticles, the thickness of
the electrical double layer drops. The heating (destruction
of electrical double layer) of aluminum nanopowder in air
and its oxidation is accompanied by a threshold effect
[13, 15]. Nazarenko et al [16] demonstrated that the electric
explosion nanopowders for 10–27 years storage generally
conserve their thermo chemical parameters. However, they
are not given in detail depending on the conditions of the
energy parameters of the electric explosion.
The goal of the present work is to determine the regu-
larities of change in chemical activity parameters of a series
[a] Prof. A. Ilyin, Prof. D. Tikhonov, A. Mostovshchikov
National Research Tomsk Polytechnic University, 30, Lenin Ave.,
634050, Tomsk, Russia
*e-mail: pasembellum@mail.ru
Short Communication
These are not the final page numbers!
ÞÞ
Propellants Explos. Pyrotech. 2018, 43, 1–6 © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 1