Electrochimica Acta 45 (2000) 3877 – 3883
Electrochemical characterization of polyaniline – molybdenum
trisulfide electrode in non-aqueous media
Florence Fusalba, Daniel Be ´langer *
De ´partement de Chimie, UQAM, Case Postale 8888 Succursale Centre -Ville, Montreal, Que ´bec, Canada H3C 3P8
Received 27 July 1999; received in revised form 8 November 1999
Abstract
Polyaniline (PANI) – molybdenum trisulfide (MoS
3
) electrode, prepared by a multi-step procedure, and polyaniline
electrode were characterized in non-aqueous electrolyte (0.5 M LiClO
4
/acetonitrile) by cyclic voltammetry, electro-
chemical impedance spectroscopy and the electrochemical quartz crystal microbalance (EQCM). The voltammetric
charge decreased slightly (20%) upon incorporation of MoS
3
in the PANI film electrode. The normalized low
frequency capacitance defined as the low frequency capacitance/voltammetric charge ratio is identical for both PANI
and PANI–MoS
3
electrodes suggesting that MoS
3
does not contribute to the capacitance measured. The EQCM data
is consistent with mixed transport of anions and cations. Upon oxidation in 0.5 M LiClO
4
/acetonitrile, a mass change
of 43 g/mol is observed for PANI–MoS
3
and this suggests that solvent is also involved in addition to ClO
4
-
ingress
and Li
+
expulsion. © 2000 Elsevier Science Ltd. All rights reserved.
Keywords: Polyaniline; Conducting polymers; Molybdenum trisulfide; Electrochemical quartz crystal microbalance; Composite
www.elsevier.nl/locate/electacta
1. Introduction
Research on active electrode materials for recharge-
able lithium batteries is extremely active at the present
[1]. Both anode (e.g. carbon-based materials) and
cathode materials are being investigated by several re-
search groups worldwide. For the latter, one-dimen-
sional transition metal chalcogenides, layered metal
oxides and chalcogenides and three-dimensional transi-
tion metal oxides have been prepared by various routes
and systematically investigated [1,2]. On the other
hand, conducting polymers such as polyacetylene,
polypyrrole, polyaniline (PANI) and polythiophene [3]
have been proposed as active electrode materials for
lithium batteries but much less work has been per-
formed on these materials relative to the inorganic
materials mentioned above.
More recently, conducting polymer-based composites
with organic sulfide [4–6], transition metal oxides [7–
10] and transition metal sulfide [11,12] were prepared
with the aim of improving the charge capacity and the
electronic conductivity of the resulting electrode mate-
rial. These molecular composites were prepared by
chemical polymerization of the conducting polymer in-
side an inorganic host [8–10] and by the coelectrodepo-
sition of a conducting polymer such as polypyrrole with
a transition metal sulfide, ex. molybdenum trisulfide
(MoS
3
) [12]. However, we have recently shown that
PANI–MoS
3
cannot be prepared electrochemically in
one step and a multistep procedure was developed for
its preparation [11]. It involved the electrochemical
polymerization of PANI followed by the chemical for-
mation of MoS
3
within the porous PANI matrix.
In this paper, we report the electrochemical charac-
terization of PANI – MoS
3
composite in non-aqueous
electrolyte by cyclic voltammetry, electrochemical
impedance spectroscopy and electrochemical quartz
* Corresponding author. Fax: +1-514-987-4054.
E-mail address: belanger.daniel@uqam.ca (D. Be ´langer).
0013-4686/00/$ - see front matter © 2000 Elsevier Science Ltd. All rights reserved.
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