Thermal Performance of Ionic Liquids for Solar Thermal Applications
Titan C. Paul, A.K.M. M. Morshed, Elise B. Fox
1
, Ann E. Visser
1
, Nicholas J. Bridges
1
, Jamil A. Khan
Department of Mechanical Engineering
University of South Carolina, Columbia, SC, USA
1
Savannah River National Laboratory, Aiken, SC, USA
ABSTRACT
Experimental investigations were carried out to evaluate thermophysical properties, i.e.density,
viscosity, heat capacity, and thermal conductivity and high temperature forced convection
behavior of N-butyl-N,N,N-trimetylammoniumbis(trifluormethylsulfonyl)imide ([N
4111
][NTf
2
])
ionic liquid (IL) for its potential application in concentrated solar power (CSP). Results from the
experiments will be useful in assessing the potential of using ILs for solar thermal collectors.
Experimental results show that thethermal conductivity was slightly decrease with the increase of
temperature; vary from 0.124 to 0.121 W/m.K for a change in temperature of 283-343K, strong
temperature effect on the viscosity of IL was observed and maintain an exponential relationship
with the temperature; heat capacity increases linearly with temperature measured from 298-
618K. Forced convection performance of the IL was studied in a circular tube under both in
laminar and turbulent conditions. Although the heat transfer coefficient of the IL was found to be
lower compared to the De-Ionized (DI) water, its thermal stability and other attractive properties
may make it a viable candidate for solar collector use. Our experimental results also established
that Shah’s equation and Gnielinski's equation can predict forced convection performance of IL
for both the laminar region and turbulent region respectively.
Keywords: Ionic Liquid; Heat Capacity; Thermal Conductivity; Convective Heat Transfer
Coefficient; Nusselt number; Reynolds number.
*Corresponding Author
Dr. Jamil A Khan
Department of Mechanical Engineering
University of South Carolina, Columbia, SC 29208
E-mail: khan@cec.sc.edu
Phone: 1-803-777-1578
© 2014. This manuscript version is made available under the Elsevier user license
http://www.elsevier.com/open-access/userlicense/1.0/