Available online at www.sciencedirect.com ScienceDirect Materials Today: Proceedings 4 (2017) 10489–10493 www.materialstoday.com/proceedings 2214-7853 © 2017 Elsevier Ltd. All rights reserved. Selection and Peer-review under responsibility of International Conference on Recent Trends in Engineering and Material Sciences (ICEMS- 2016). ICEMS 2016 Solution Combustion Synthesis of Perovskite-type Catalysts for Diesel Engine Exhaust gas Purification Ganesh chandra Dhal a* , Subhashish Dey a , Devendra Mohan a , Ram Prasad b a Department of Civil Engineering, Indian Institute of Technology (BHU), Varanasi, India b Department of Chemical Engineering & Technology, Indian Institute of Technology (BHU), Varanasi, India Abstract Solution Combustion synthesis has been applied to LaFeO 3 production with a view to boosting its activity for diesel engine exhaust gas purification by enhancing its specific surface area. With a highly exothermic and self-sustaining reaction, this oxide can be quickly prepared from an aqueous solution of metal nitrates (oxidisers) and urea (fuel). The favourable conditions for LaFeO 3 formation were sought: only fuel-rich mixtures are effective, but carbonaceous deposits are formed when too much urea is used. Under operating conditions in which the combustion synthesis reaction takes place, the specific surface areas were not dramatically higher than those obtained with traditional methods; moreover, even short thermal treatments have been found to rapidly deactivate the catalysts by rapid sintering with a view to tackling these problems, NH 4 NO 3 was chosen as an additive for its low costs, highly exothermic decomposition and also because it generates gaseous products only, without altering the proportion of the other elements in the catalysts. With ammonium nitrate, specific area was enhanced from 4 m 2 /g up to about 20 m 2 /g. A short thermal treatment at 900 °C partially deactivates also the NH 4 NO 3 -derived catalysts. It was found that NH 4 NO 3 - boosted mixtures produce materials whose activity, after a similar thermal treatment, is practically the same as the perovskites obtained by the “citrates” method. Combustion synthesis is though rather cheap-in terms of reactants employed and quick, because the process requires few minutes at low temperature without successive calcination. However, the main drawback of this method is that hazardous or polluting compounds are emitted during the synthesis (mainly NH 3 or NO X ). © 2017 Elsevier Ltd. All rights reserved. Selection and Peer-review under responsibility of International Conference on Recent Trends in Engineering and Material Sciences (ICEMS-2016). Keywords: SCS, nitrate precursors, organic fuel, Diesel particulate, Perovskite catalyst, Diesel Engine Exhaust, CO/NO emissions * Corresponding author. Tel.: +91 7752957691; fax: 0542-2307016. E-mail address: ganesh.dhal@gmail.com