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z Medicinal Chemistry & Drug Discovery
Synthesis and Antibacterial Evaluation of New Pyrimidyl N-
Ciprofloxacin Derivatives
Majid Mokaber-Esfahani,
[a, b]
Hossein Eshghi,*
[a]
Marzieh Akbarzadeh,
[a]
Mostafa Gholizadeh,
[a]
Yahya Mirzaie,
[c]
Mohammad Hakimi,
[c]
and Jalil Lari
[c]
Herein, nucleophilic substitution reaction of pyrimidine deriva-
tives on piperazine in ciprofloxacin resulted in the formation of
new pyrimidyl N-ciprofloxacines. These compounds were
prepared at room temperature, at conventional heating and
under microwave irradiation conditions. Results indicated
microwave condition as a green approach in comparison with
room temperature and at conventional heating condition leads
to higher yields and very short reaction times.
1
H,
13
C-NMR, FT-
IR, Mass spectroscopy and CHN analysis were used to character-
ize all the synthesized products. Meanwhile, the antibacterial
activity of these new compounds against gram-positive and
gram-negative bacteria was investigated and showed more
activities for two new N-ciprofloxacin derivatives than cipro-
floxacin.
Introduction
Microwave-assisted organic synthesis complies with the princi-
ples of green chemistry that has attracted increasing interest in
drug discovery. These reactions, which were assisted to
excellent chemical/thermal stability and good solvating ability,
displayed significant merits by their reduced reaction time, the
simplicity of processing, improved yields, low pollution and
eco-friendly method
[3À6]
.
Heating reactions with oil bath are the most common
method for the preparation of organic compounds. This
method is time-consuming and with the making of a hot
surface on the reaction vessel often results in decomposition of
materials over time and therefore, low efficiency is inevitable.
These problems and the priority of chemical industries to do
reactions with low times and high yields have resulted in using
microwave energy. In microwave method, microwave irradi-
ations pass through the walls of the reaction vessel and the
reactants and solvent heat directly, and then conversion of
electromagnetic radiation to heat in a chemical reaction and
selective absorption cause an acceleration of reaction. In this
strategy, an increase in uniform temperature in the sample and
decrease of by-products or product decomposition were
showed
[9À11]
. Quinolones have emerged as molecules with
useful properties that have gained considerable attention on
medical chemists due to their biological activity. They are
synthetic antibacterial compounds with a 4-quinolone skeleton.
Interaction of quinolone with two essential bacterial type II
topoisomerases, DNA gyrase and DNA topoisomer IV that both
are require for cell growth and division, causes inhibition of
their DNA synthesis. Therefore quinolones introduced as
antibacterial compounds. Nalidixic acid was the first quinolone
that used as an antibacterial agent and then modification on its
basic structure (quinolone) produced new compounds with
improved antibacterial activity
[15À18]
. Fluoroquinolones, includ-
ing ciprofloxacin and ofloxacin, are important antibacterial
agents used in various infectious diseases
[19]
. However, the
growing of fluoroquinolones usage has impacted against the
gram-negative bacteria, while they acted comparatively moder-
ate against gram-positive bacteria. Also, some of them function
as anticancer and anti-HIV inhibitors
[22,23]
. Nowadays, for the
discovery of new antimicrobial agents, direct manipulation of
the structure of available antibacterial agents is a practical
approach to improve antimicrobial efficacy. Although fluoro-
quinolones have major application for clinical use, researchers
attempt to improve their characters in the hospital applications
via the structural modification of their framework. It has been
found that C-7 substituent of fluoroquinolones is responsible
for drug-enzyme interactions and the control of cell perme-
ability. In this regard, substitutions on piperazine ring in 6-
fluoro-7-piperazinylquinolone compounds, which carried out
through nucleophilic aromatic substitution reaction on the
corresponding halides produced new fluoroquinolones.
In this work, we synthesized pyrimidyl N-ciprofloxacines by
nucleophilic substitution H atom of piperazine in ciprofloxacin
with various pyrimidine moieties (Scheme 1). We used three
strategies for the synthesis of these compounds, first at room
temperature, then with microwave irradiation and finally in
conventional heating. eventually antibacterial activity of new
products was reported. However, despite a good yield of the
first reaction, its application was limited due to the above
problems and advantages of microwave irradiation including
[a] Dr. M. Mokaber-Esfahani, Prof. H. Eshghi, Dr. M. Akbarzadeh,
Prof. M. Gholizadeh
Department of Chemistry, Faculty of Science, Ferdowsi University of
Mashhad, 91775-1436 Mashhad, Iran
E-mail: heshghi@um.ac.ir
[b] Dr. M. Mokaber-Esfahani
Department of Chemistry, Faculty of Science, Gonbad Kavous University,
Gonbad Kavous, Iran
[c] Dr. Y. Mirzaie, Prof. M. Hakimi, Dr. J. Lari
Department of Chemistry, Payame Noor University, 19395-3697 Tehran,
Iran
Supporting information for this article is available on the WWW under
https://doi.org/10.1002/slct.201901924
Full Papers DOI: 10.1002/slct.201901924
1 ChemistrySelect 2019, 4,1–5 © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim