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Journal of Building Engineering
journal homepage: www.elsevier.com/locate/jobe
Effects of rice straw ash and micro silica on mechanical properties of
pavement quality concrete
Arunabh Pandey
*
, Brind Kumar
Department of Civil Engineering, IIT (BHU), Varanasi, 221005, India
ARTICLE INFO
Keywords:
Rice straw ash
Microsilica
Compressive strength
Flexural strength
Split tensile strength
XRD
SEM
ABSTRACT
This research deals with improvement in the mechanical strength of Pavement Quality Concrete (PQC) when
admixed with Rice Straw Ash (RSA) and Microsilica (MS). Nine mixes were prepared by partially substituting
Ordinary Portland Cement (OPC) by MS (2.5%, 5%, 7.5%, and 10%), RSA (10%) and RSA-MS composite
(5%–5%, 5%–7.5%, 10%–5% and 10%–7.5%). Maximum improvement was found when OPC was partially re-
placed by 7.5% in the case of MS and 5%–7.5% in case of RSA-MS composite. All the mix showed increased
strength, w.r.t the control mix. X-Ray powder diffraction (XRD) and Scanning Electron Microscope (SEM)
techniques were employed for characterization of the selected samples. Power regression equations were es-
tablished to predict split tensile and flexural strength from compressive strength. They were compared with
universally accepted equations and were found to be more accurate for RSA and MS admixed concrete. Mix
R1M3 (5% RSA, 7.5% MS) is recommended based on the findings.
1. Introduction
The construction sector of India is growing at a rapid rate and ce-
ment is the most important material required in the construction sector.
In fact, India is the largest producer of cement in the world behind
China. The capacity of cement plants in India was around 502 million
tonnes in 2018 [1]. The production of cement raises serious environ-
mental concerns like emission of carbon dioxide gas (CO
2
)[2]. Emis-
sion of carbon dioxide gas causes the greenhouse effect. In fact, cement
plants account for 5% of the global emission of CO
2
. Around 900 kg of
CO
2
is liberated into the atmosphere in production of 1000 kg of cement
[3]. As the consumption of cement is increasing day by day, a reduction
in CO
2
emissions can be done by partially substituting OPC with mi-
neral admixtures. Mineral admixtures such as rice straw ash [4–8] and
micro silica [9–12] can be a feasible solution for partial replacement of
OPC in PQC, thus reducing the emission of CO
2
. The resulting ce-
mentitious material will be cheaper, resulting in more affordable con-
crete for pavement construction.
Rice straw is an agricultural by-product of rice. It is mainly pro-
duced in Asia where its yearly production is 95% of world production
[13]. Rice straw production is highest among the agro-residues pro-
duction in India [14]. Traditionally rice straw has numerous competing
uses such as animal feed, fodder, fuel, roof thatching, packaging and
composting. These uses, however, will soon diminish because advanced
technologies are making them unprofitable. Rice straw can be con-
verted into ash without using enhanced burning techniques. When rice
straw is burnt, it produces ash which is highly pozzolanic and fulfils the
necessities of ASTM C618-19 [15] Class N, F, and C pozzolan. The
specific gravity and specific surface area of rice straw ash are 2.25 and
1.846 m
2
/g, respectively [5].
Micro silica is an indistinguishable (non-crystalline) polymorph of
silicon dioxide, silica. It is an ultrafine powder gathered as a by-product
of the silicon and ferrosilicon composite production and comprises
spherical particles with an average particle diameter of 150 nm [12].
There has been less amount of work done to explore the possible
results of using rice straw ash in PQC and even less number of these
explorations tends to the use of natural RSA in PQC (RSA that is either
not ground to fine particle sizes and/or that isn't produced by an en-
hanced burning technique). The present study is the continuation of the
work in which analysis of rice straw ash was done by its chemical,
mineralogical, thermal and structural properties [6]. Also, a pre-
liminary study was done on the cement paste containing rice straw ash,
microsilica, and their composite by finding out its normal consistency
and setting times [7]. The compressive strength of the mortar cubes of
various proportions was determined after 3, 7, 28, 60, 90 and 365 days
of curing in water [16]. It was found out that the mortar cubes of mix
M3 (7.5% microsilica) give the maximum strength.
The principal purpose of this analysis is to develop the use of rice
https://doi.org/10.1016/j.jobe.2019.100889
Received 23 February 2019; Received in revised form 1 June 2019; Accepted 19 July 2019
*
Corresponding author.
E-mail address: arunabh.rs.civ13@iitbhu.ac.in (A. Pandey).
Journal of Building Engineering 26 (2019) 100889
Available online 20 July 2019
2352-7102/ © 2019 Elsevier Ltd. All rights reserved.
T