IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 19, NO. 3, JUNE 2009 3231
The Development of Second Generation HTS
Wire at American Superconductor
Xiaoping Li, MartinW. Rupich, Cornelis L. H. Thieme, M. Teplitsky, Srivatsan Sathyamurthy, E. Thompson,
D. Buczek, J. Schreiber, K. DeMoranville, J. Lynch, J. Inch, D. Tucker, R. Savoy, and S. Fleshler
Abstract—Second Generation (2G) YBCO High Temperature
Superconductor wire, based on the RABiTS/MOD process, is now
being produced in continuous lengths at American Supercon-
ductor (AMSC) using a full-scale, reel-to-reel manufacturing line.
AMSC’s approach for manufacturing 2G wire is designed around
a low-cost, wide-strip technology, in which a 4-cm wide strip is
slit into multiple narrower wires, then laminated to metallic stabi-
lizers producing a 3-ply wire called 344 superconductors. A major
advantage of this approach is the ability to tailor the electrical,
mechanical and thermal properties and dimensions of the final
wire for specific applications and operating conditions. This allows
the final wire properties to be tuned for targeted applications,
including cables and fault current limiters, by tailoring the resis-
tivity and thickness of the stabilizer layers. The superconducting
properties of the MOD-based YBCO are also being improved
by the introduction of thicker YBCO layers and improved flux
pinning centers. This paper describes the present status of 2G
wire manufacturing at AMSC, reviews present and projected
performance of the 344 superconductors, and summarizes initial
application demonstrations utilizing 344 superconductors.
Index Terms—Coated conductors, HTS, RABiTS, YBCO, 2G
wire.
I. INTRODUCTION
S
ECOND generation (2G) high temperature supercon-
ducting (HTS) wires have moved out of the laboratory
and are now being produced in the quantity, and with the
performance, required for large-scale commercial application
demonstrations. 2G wire is now supplanting first generation
(1G) HTS wire, based on a multifilamentary composite in a
silver matrix, in most HTS-based wire applications [1]–[3].
Two major advantages of the 2G technology pioneered by
AMSC, over the first generation (1G) HTS wire, include lower
cost and the ability to tailor the wire properties and dimensions
for specific applications [4].
In this paper, we describe AMSC’s progress in transitioning
the 2G wire process from an R&D “pre-pilot”-scale to high
Manuscript received August 25, 2008. First published June 30, 2009; current
version published July 15, 2009. This work was supported in part by the US
Department of Energy, the Office of the Secretary of Defense-Title 3.
The authors are with American Superconductor, Devens, MA 01434,
USA (e-mail: xli@amsc.com; mrupich@amsc.com; cthieme@amsc.com;
mteplitsky@amsc.com; ssathyamurthy@amsc.com; ethompson@amsc.com;
dbuczek@amsc.com; jschreiber@amsc.com; kdeMoranville@amsc.com;
jlynch@amsc.com; jinch@amsc.com; dtucker@amsc.com; rsavoy@amsc.
com; sfleshler@amsc.com).
Color versions of one or more of the figures in this paper are available online
at http://ieeexplore.ieee.org.
Digital Object Identifier 10.1109/TASC.2009.2020570
Fig. 1. Schematic illustration of the “wide-strip” manufacturing process for
manufacturing low-cost 2G wire at AMSC.
volume, production-scale manufacturing and review the prop-
erties of the initial 2G HTS wire being produced in AMSC’s
production-scale facility.
II. AMSC’S 2G “WIDE-STRIP”MANUFACTURING PROCESS
AMSC’s approach to manufacturing 2G HTS wire is based
on the RABiTS/MOD technology using a “wide-strip” manu-
facturing process [2], [4]. For initial operation of the full-scale
production equipment, we have chosen to use 4-cm wide strips.
The “wide-strip” manufacturing process, illustrated in Fig. 1,
relies on the deformation-texturing of a metal alloy (Ni5at%W)
substrate and recrystallization in a reel-to-reel system to form
a cube-textured alloy template [5], [6]. The buffer layers, con-
sisting of a 75 nm thick seed layer, a 75 nm YSZ barrier
layer and a 75 nm cap layer are deposited by high-rate
reactive sputtering.
A rare earth doped YBCO precursor film is slot-die
coated onto the buffered substrate at a loading of 4800 mg
of template (calculated thickness
of 0.8 ), pyrolyzed at and con-
verted to an epitaxial film at 750–800 in
a reel-to-reel system. The YBCO strip is capped with a Ag
layer, and oxygenated at . The Ag coated strip is then
slit to the desired width and laminated between two metallic
stabilizer strips to form the superconducting wire. The standard
wire product, called 344 superconductors (Fig. 2), is prepared
from a 4-mm slit ‘insert wire’ and has equivalent dimensions to
the First Generation (1G) BSCCO HTS wire. The composition
of the stabilizer strip is indicated by the addition of a letter to
the wire name, i.e. 344B of brass and 344S for stainless steel.
The “wide-strip” process is designed to be inherently low-
cost and has the flexibility to produce wire with varying dimen-
sions and properties which can be tailored for specific applica-
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