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International Journal of Chemical Studies 2018; 6(5): 2228-2231
P-ISSN: 2349–8528
E-ISSN: 2321–4902
IJCS 2018; 6(5): 2228-2231
© 2018 IJCS
Received: 22-07-2018
Accepted: 23-08-2018
BW Tukura
Department of Chemistry,
Nasarawa State University,
Keffi Nigeria
PC Madu
Department of Science
Laboratory and Technology,
Federal Polytechnic, P.M.B 001,
Nasarawa, Nigeria
Y Usman
Department of Science
Laboratory and Technology,
Federal Polytechnic, P.M.B 001,
Nasarawa, Nigeria
BL Gav
Department of Chemistry,
Federal University of Agriculture
P.M.B 2373, Makurdi, Nigeria
Correspondence
BW Tukura
Department of Chemistry,
Nasarawa State University,
Keffi Nigeria
Assessment of heavy metal contaminants of used
engine oil around automobile workshop in
Nasarawa local Government area, Nasarawa state,
Nigeria
BW Tukura, PC Madu, Y Usman and BL Gav
Abstract
The study was carried out on assessment of heavy metal contaminants of used engine oil around
automobile workshops in Nasarawa Local Government Council, Nasarawa State, Nigeria. Samples of
Soil, water, fluted pumpkin leaves, spinach and used engine oil were collected from selected mechanic
workshops within the Nasarawa Local Government Area for both rainy and dry seasons were analyzed
for heavy metal concentrations. These samples were subjected to analysis for eight elements; Co, Zn, Cd,
Cu, Ni, Mn, Cr and Pb using Inductively Coupled Atomic Absorption Spectrophotometer. The results of
the analysis carried out for both rainy and dry seasons showed clearly that there is more concentration of
the heavy metals analyzed in the dry season than that of the rainy season. The result also shows that apart
from the mechanic workshop, some of the metals have high concentrations in some control samples. The
results of the analysis showed that most of the heavy metals examined in some samples were above the
World Health Organization limit for human consumption.
Keywords: Heavy metals, used engine oil, automobile workshop, soil, water, Amaranthus Habridus
Introduction
The increase in population worldwide has led to a high level of industrialization and
urbanization which in turn have led to environmental pollution arising from the indiscriminate
discharge of industrial effluents. These effluents may contain most common heavy metals,
such as Hg, Zn, Cu, Co, Pb, Cr (Madu et al., 2007)
[12]
. It is known that pollution through
heavy metal has become increasingly more in recent years, not only because people are more
sensitive on this subject but also because the amount of pollution has increased markedly.
There is need for research and public information on these metals, otherwise unknown dangers
may create irreparable environmental damage. Since 1999, thousands of cars, Lorries, motor
cycles are coming into Nigeria and the number of mechanic villages are increasing at a very
high rate and consequently the amount of used automotive oil being disposed everyday has
equally increased (Madu et al.,2007)
[12]
.
Waste automotive oil can be defined as oil that has picked up foreign substances, or
contaminants. This can occur before, during or after use (CCME, 2002). Waste automotive oils
collect contaminant in many ways depending upon the original use of the oil. In general, waste
automotive oils contain oxidation products, sediments, water and metallic particles resulting
from machinery wear. In addition to these, waste automotive oil also contains gasoline fuels,
organic and inorganic chemicals used in oil additives and metals which were present in
gasoline and transferred to the crankcase during combustion (Adebayo et al., 2004)
[1]
. Lead is
the principal metallic contaminant found in waste automotive oils being present in amounts
which sometimes exceed one percent by weight (Olonisakin et al., 2005)
[14]
.
Heavy metals are natural components of the earth crusts. They are stable and persistent
environmental contaminants of coastal waters and sediments. Since they cannot be degraded or
destroyed to a small extent, they enter our bodies via food chain, drinking water and air
(Lawrence, 1990)
[9]
. Examples of heavy metals include mercury (Hg), cadmium (Cd) Arsenic
(Ar) chromium (Cr) Lead (Pb) Nickel (Ni) Zinc (Zn), and Selenium (Se). Interest in metals
like Zinc, Copper, Iron and Selenium which are required for metabolic activity in organisms
lies in the narrow path between their essentiality and toxicity. Other heavy metals like lead,
cadmium and mercury may exhibit extreme toxicity even at low levels under certain