Jurnal Ilmu Fisika
Vol. 15, No. 2, September 2023, pp. 91-105
ISSN: 1979-4657 (Print); 2614-7386 (Online)
https://doi.org/10.25077/jif.15.2.91-105.2023
Attribution-NonCommercial 4.0 International http://jif.fmipa.unand.ac.id/ 91
Open Access
Jurnal Ilmu
Fisika
Synthesis of Fluorescent Carbon Dots (CDs) Using Laser Ablation Method
for Bioimaging Application
Jumardin Jumardin
1
, Akhiruddin Maddu
2
, Kokoeh Santoso
3
, Isnaeni Isnaeni
4
1
Department of Physics, Faculty of Sciences and Technology, Alauddin State Islamic University of Makassar
Gowa, 92113, Indonesia
2
Department of Physics, Faculty of Mathematics and Natural Sciences, IPB University, Bogor, 16680, Indonesia
3
Department of Anatomy, Physiology and Pharmacology, School of Veterinary and Biomedical, IPB University
Bogor, 16680, Indonesia
4
Research Center for Photonics, National Research and Innovation Agency (Badan Riset dan Inovasi Nasional, BRIN)
BJ Habibie Science and Technology Park, Banten 15314, Indonesia
Article Info ABSTRACT
Article History:
Received January 17, 2023
Revised March 12, 2023
Accepted April 19, 2023
Published online May 06, 2023
Carbon Dots (CDs) were synthesized using laser ablation by focusing the laser
beam on carbon (Tea) material in colloid (CH
3
) for 3 hours. UV-Vis
spectroscopic and fluorometric characterization showed absorption of the
wavelength peaks caused by the control treatment and after laser ablation and
coating using Poly Ethylene Glycol (PEG
400
). The excitation and emission
energies are formulations of CDs absorbance wavelength and fluorescence
intensity. The absorbance coefficient is obtained based on the absorbance value
of the cuvette thickness. The transmittance value (T) is obtained based on the
absorption coefficient multiplied by 100%. CD fluorescence wavelength based
on control parameters was 489 nm. After laser ablation was 496 nm, and after
coating was 511 nm. CDs morphology and size characteristics are 4 nm to 10
nm based on TEM measurements. Fluorescence analysis for bioimaging
applications on the luminescence intensity value of internalized blue CDs in
zebrafish eye organs. The average intensity of CDs in the eye organs, gill,
intestinal, dorsal, and tail injection points was 88.15 %, 91.58 %, 92.76 %, and
0.00 %.
Copyright © 2023 Author(s)
Keywords:
Carbon dots
Laser ablation
Fluoresccent
Bioimaging
Corresponding Author:
Jumardin Jumardin
Email: jumardin.jumardin@uin-
alauddin.ac.id
1. INTRODUCTION
Carbon Dots (CDs) are zero-dimensional nanomaterials (Liang et al., 2020) in the carbon nano
group with a size of less than 10 nm (Alkian et al., 2022). CDs exhibit stable photoluminescence, good
biocompatibility (Dias et al., 2019), and low toxicity to various cells (Emam et al., 2017), and thus have
potential as bioimaging materials (Li et al., 2020). Luminescence from CDs is the event of the
appearance of visible light by a particular substance (Zhang et al., 2021) after absorption of radiant
energy (Wang et al., 2009). A luminescence event is caused by electrons that absorb the radiant energy,
and these electrons move to higher orbitals, exciting the material molecules into an excited state. The
Fluorescence that occurs in CDs is due to the excited molecules returning to their ground state by
releasing energy through the emission of photons. The Fluorescence of CDs is of great interest because
it fluoresces in biological materials (living cells) and can be modified for biomedical applications
(Phukan et al., 2022). They use this property in biomedical applications, Fluorescence for increased