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FEATURE ARTICLE
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electron transport, lack of skin effect, cur-
rent carrying capacity exceeding super-
conductors, mechanical strength/stiffness
better than any metal, thermal conductivity
exceeding diamond and many other prop-
erties. This amazing list can be extended
by advantages such as the wide availability
of carbon sources, the potential low-cost of
large-scale production and their zero net
carbon footprint, together these attributes
make carbon nanotubes an obvious candi-
date for “the material of the future”.
One very interesting potential applica-
tion of carbon nanotubes is in electrical
wiring. Conventional electrical wires made
of copper and aluminium suffer from sev-
eral problems including: weight (an issue
in aerospace applications), skin effect (hindering their use in
modern telecommunications), mechanical performance (critical
in overhead power lines), and electromigration (severely dam-
aging microscopic wires in electronics applications). Moreover,
the growing demand for these conventional metal conductors
and their continually increasing prices suggests that a low-cost
material that can outperform conventional conductors would be
highly desirable. Hence, carbon nanotubes are the material of
great interest.
However, there are several challenges in the production of
carbon nanotube electrical wires and their application, which
include; preparation of macroscopic structures that retain
the properties of individual nanotubes, control over the mor-
phology and dimensions of these structures, development of
large-scale cost-effective manufacturing processes and pro-
viding the wires with suitable electrical insulation and connec-
tions for integration into electrical systems. Not less impor-
tant, is the in-depth understanding of the physics behind
the transport properties of these new carbon structures and
possible preparation of new standards for the use of the CNT
wires. Some of the solutions to these issues have been already
suggested.
Several research groups have already succeeded in the pro-
duction of macroscopic CNT fibers (also referred to as yarns
or threads) which are long assemblies of axially aligned nano-
tubes, of diameters in the micrometer range.
[2–4]
The theoretical and experimental research on CNT fibers
predict that proper control of the morphology of these macro-
scopic assemblies of CNTs should produce the material of
excellent electrical conductivity comparable to the conductivity
of individual nanotubes.
[5]
Electrical Properties of Carbon Nanotube Based Fibers
and Their Future Use in Electrical Wiring
Agnieszka Lekawa-Raus, Jeff Patmore, Lukasz Kurzepa, John Bulmer,
and Krzysztof Koziol*
The production of continuous fibers made purely of carbon nanotubes has
paved the way for new macro-scale applications which utilize the superior
properties of individual carbon nanotubes. These wire-like macroscopic
assemblies of carbon nanotubes were recognized to have a potential to be
used in electrical wiring. Carbon nanotube wiring may be extremely light
and mechanically stronger and more efficient in transferring high frequency
signals than any conventional conducting material, being cost-effective simul-
taneously. However, transfer of the unique properties of individual CNTs to
the macro-scale proves to be quite challenging. This Feature Article gives an
overview of the potential of using carbon nanotube fibers as next generation
wiring, state of the art developments in this field, and goals to be achieved
before carbon nanotubes may be transformed into competitive products.
1. Introduction
The ever increasing use of technology in all areas of our daily life
has had an immense effect on our demand for electrical energy,
and this has resulted in the urgent need to find more efficient
methods for its generation and distribution. This need has stimu-
lated the quest for new materials and highly efficient devices,
which have significantly better performance than those currently
in use, as well being cost-effective, safe, and environmentally
friendly. In this perspective, carbon is a very promising material.
The recent synthesis of fullerenes, carbon nanotubes and
separation of graphene has generated enormous interest in
these carbon materials.
[1]
Carbon allotropes of this type offer
not only a highly exciting and vast area for scientific exploration
but also the potential for a wide spectrum of novel engineering
applications due to their properties.
Carbon nanotubes are particularly attractive, due to their
tubular shape, low density, tuneable electrical properties, ballistic
DOI: 10.1002/adfm.201303716
Dr. A. Lekawa-Raus, L. Kurzepa, J. Bulmer, Dr. K. Koziol
Department of Materials Science and Metallurgy
University of Cambridge
CB3 0FS, UK
E-mail: kk292@cam.ac.uk
J. Patmore
Pembroke College
Cambridge CB2 1RF, UK
This is an open access article under the terms of the Creative Commons
Attribution-NonCommercial License, which permits use, distribution
and reproduction in any medium, provided the original work is properly
cited and is not used for commercial purposes.
Adv. Funct. Mater. 2014, 24, 3661–3682