Journal of Building Engineering 31 (2020) 101370
Available online 26 March 2020
2352-7102/© 2020 Elsevier Ltd. All rights reserved.
Contents lists available at ScienceDirect
Journal of Building Engineering
Water absorption and sorptivity of alkali-activated ternary blended
composite binder
Md Maruf Hossain
a, *
, Md Rezaul Karim
b, **
, Md Manjur A Elahi
c
,
Muhammad Fauzi Mohd Zain
d
a
Faculty of Engineering and Built Environment, The University of Newcastle, Callaghan, Australia
b
Department of Civil Engineering, Dhaka University of Engineering & Technology, Gazipur, Bangladesh
c
Project Engineer, Construction Services Department, Intertek - PSI, Houston, TX, United States
d
Faculty of Engineering and Built Environment, University Kebangsaan Malaysia, Selangor, 43600, Malaysia
ARTICLE INFO
Keywords:
Pozzolans
Alkali-activated binder
Water transport properties
Water absorption
Sorptivity
ABSTRACT
This study examined the crucial durability properties of cementitious materials named water absorption and
sorpitivity of two alkali-activated binders (AAB) namely AAB-1 and AAB-2, which incorporated a different
composition of pozzolans including rice husk ash, fy ash, palm oil fuel ash, and slag. NaOH with a concentra-
tion of 2.5 M was used to activate these binders. While the water absorption was measured at 28, 90, 180, and
270 days the sorptivity test was performed at 90, 180, and 270 days on mortar specimens. The test result indi-
cates the AABs absorbed more water than OPC, especially at the initial period, which reduced over the curing
period. Porous microstructure and consequential lower compressive strength of AABs has been considered re-
sponsible for this. Similarly, the sorptivity value was higher for both AAB than OPC. The higher water absorp-
tion and lower strength of AABs lead to a higher sorptivity. The water transport properties can be improved
through increasing the strength and making a dense microstructure by optimizing the properties of pozzolans
and the mixture composition of AAB.
1. Introduction
To curtail the ever-increasing CO
2
emission, the experts from the
academia and industry have been moving toward to develop a ce-
ment-free and sustainable binder by using pozzolanic materials in-
cluding slag, fy ash (FA), palm oil fuel ash (POFA) and rice husk ash
(RHA). A wide range of studies were conducted in the feld of alkali-
activated binders (AAB) by using slag and FA that were activated with
NaOH, KOH and Ca(OH)
2
separately or in combination with sodium/
potassium silicate [1 –5]. It is explicitly reported that the AAB has the
potential to impart mechanical properties including compressive
strength, splitting tensile strength and elastic modulus at early age as
well as it is less energy-intensive and releases less CO
2
into the atmos-
phere than conventional OPC [6 –10].
Many researchers reported that AAB containing slag show an effec-
tive strength and mechanical properties along with improved durabil-
ity properties. El-Sayed el al [11]. studied durability and mechanical
properties of water-cooled slag using a combination of sodium hy-
droxide and sodium silicate activator where an equivalent dosage
(3:3) of these two activators outperformed different dosage of sodium
hydroxide. On the other hand, in another study on activated slag,
sodium silicate was reported to perform better followed by sodium
carbonate and sodium hydroxide with exactly same molar concentra-
tion [12]. Vance et al. [13] also examined mechanical properties of
activated slag concrete where 2.0 M was observed as optimum among
1.0 M; 1.5 M and 2.0 M. In a review on the performance of fy ash
based activated binder, Al Bakri et al. [14] highlighted the molar con-
centration, types, curing conditions as the infuential factors. Thok-
chom et al. [15] examined the acid resistance of fy ash based
geopolymer and observed no impact while Wallah reported a negligi-
ble drying shrinkage of heat-cured fy ash concrete [16]. The effect of
curing method and molar concentration of NaOH on compressive
strength and durability (acid and sulfate) of activated RHA based
mortar was studied by Kim et al. [17] where increased curing period
*
Corresponding author.
**
Corresponding author.
E-mail addresses: md.maruf.hossain@uon.edu.au (M.M. Hossain), rezaul@duet.ac.bd (M.R. Karim).
https://doi.org/10.1016/j.jobe.2020.101370
Received 1 August 2019; Received in revised form 2 December 2019; Accepted 21 March 2020