Vol.:(0123456789)
Polymer Bulletin
https://doi.org/10.1007/s00289-019-02919-4
1 3
ORIGINAL PAPER
The application of green synthesis of metal oxide
nanoparticles embedded in polyethylene terephthalate
nanofbers in the study of the photocatalytic degradation
of methylene blue
Suhad A. Yasin
1
· Jamal A. Abbas
1
· Ibtisam A. Saeed
1
· Idrees H. Ahmed
1
Received: 3 April 2019 / Revised: 24 July 2019 / Accepted: 20 August 2019
© Springer-Verlag GmbH Germany, part of Springer Nature 2019
Abstract
In this study, polyethylene terephthalate (PET) nanofbers are dipped into the extrac-
tion of pomegranate leaves (Punica granatum) in aqueous solution operated as a
reducing agent to fabricate PET nanofbers with CuO nanoparticles, which are used
later for the photocatalytic degradation methylene blue (MB) in aqueous solution.
Scanning electron microscopy analysis is used to study the surface nanofber mor-
phology. UV–visible spectrophotometry is used to determine the concentration of
(MB) after photodegradation. Photodegradation of (MB) in this study has shown
that the degradation efciency is afected by many factors like time, pH, and con-
centration. The results have proved that PET nanofbers/CuO nanoparticles acquire
high photodegradation efciency in a short time.
Keywords Nanofbers · Electrospinning · Green synthesis · Methylene blue ·
Photocatalytic degradation
Introduction
Organic dye pollutants are produced by fabric, leather, and cosmetics production sign-
aling a signifcant environmental concern [1]. The problem which the world is facing
now is that organic dyes generally have a complex aromatic structure and can display
anionic, cationic, and non-ionic properties [2]. These dyes are methylene blue (MB),
crystal violet (CV), rhodamine B (RhB), methyl orange (MO), Congo red (CR), and
Remazol Black-B (RB5) [3]. The colors of these organic dyes can be observed even at
low concentration, making water highly unfavorable, which is risky to human health
and the environment [4]. Over 10,000 diferent types of organic dyes and pigments,
* Suhad A. Yasin
suhad.yasin@uod.ac
1
College of Science, University of Duhok, Duhok 42001, Iraq