0030-400X/01/9105- $21.00 © 2001 MAIK “Nauka/Interperiodica” 0779
Optics and Spectroscopy, Vol. 91, No. 5, 2001, pp. 779–785. Translated from Optika i Spektroskopiya, Vol. 91, No. 5, 2001, pp. 830–836.
Original Russian Text Copyright © 2001 by Bonch-Bruevich, Vartanyan, Leonov, Przhibel’skiœ, Khromov.
INTRODUCTION
Investigations of the structure of island films run
into a number of complicated technical problems. The
methods of investigation that have been developed up
to the present are very laborious and either are accom-
panied by the destruction of the subject being investi-
gated (electron microscopy) or require a direct combi-
nation of the evaporation chamber with the measuring
equipment (atomic force microscopy). The monitoring
of the kinetics of film growth or variations in structural
film parameters under a certain external action is partic-
ularly difficult using these methods. In addition, both
these high-resolution methods have another essential
disadvantage. They give information only about small
film areas (of the order of 1 μm
2
), and the data obtained
require subsequent processing. To solve the above-
mentioned problems, we have proposed and realized
the optical method of noncontact determination of
structural film parameters [1]. In this paper, we have
demonstrated the possibility of determining parameters
of island films such as the density of nanometer islands,
their size, and the size dispersion.
In the present study, we monitored variations in the
structural parameters of island metal sodium films on
the quartz surface during heating of the substrate and
exposure of the films to an intense optical radiation.
Recall briefly the idea of the proposed method. In
this method, the reflection and transmission of the light
beam focused on a film and scanned over it are mea-
sured. Since the sizes and the number of islands falling
within the focal spot are random quantities, the mea-
sured local optical characteristics of the film are also
random quantities. By using the measurement data of
these random characteristics of the film, one can suc-
ceed in determining the statistical characteristics of the
islands, such as the density, the mean size, and the size
dispersion. It has been shown that it is possible to
obtain the island size distribution function from the
measurement data of the evolution of the film parame-
ters under heating of the substrate or under the action of
intense optical radiation, if the law of decrease of their
sizes in time is known. In this case, it is possible to
reconstruct the distribution function at any instant of
action on the film.
RELATION BETWEEN THE STRUCTURE
OF THE FILM AND ITS OPTICAL PROPERTIES
Let us describe the technique for determining the
structural parameters from the measured data of optical
reflection and transmission coefficients for the films
deposited on the surface of a transparent dielectric. Ini-
tially note the specific features of implementation of the
proposed method. The first feature is connected with
the fact that no intrinsic optical characteristics of a film
are measured experimentally, because it is always
located on a dielectric surface. The second feature is
caused by the focus of the beam scanned over the film.
Both circumstances complicate the determination of
the inherent optical characteristics of a film based on
the measurement data. For purposes of simplification
Comparative Investigation of the Effect of Heat
and Optical Radiation on the Structure of Island Metal Films
by Optical Fluctuation Microscopy
A. M. Bonch-Bruevich, T. A. Vartanyan, N. B. Leonov,
S. G. Przhibel’skiœ, and V. V. Khromov
Vavilov State Optical Institute, All-Russia Scientific Center, St. Petersburg, 199034 Russia
e-mail: tigran@jamnet.spb.su
Received April 12, 2001
Abstract—Variations in the structural parameters of island sodium films on the quartz surface, caused by heat-
ing or exposure to optical radiation, are investigated by the optical method proposed earlier. A correct scheme
of processing the measured data is developed. It is shown that to determine the structure parameters, the mea-
surements of both the mean values and fluctuations of transmission and reflection coefficients of the film and
of their correlator are required. It is also demonstrated that under a number of assumptions, it is possible to
determine the character of the process of evaporation of islands and to reveal the evolution of the distribution
function by using the data of measurements. It was found experimentally that variations in the structural param-
eters of a film during its evaporation caused by heating of the substrate or irradiation by light can noticeably
differ. This fact is explained by a difference in the mechanisms of action of heating and irradiation on an island.
© 2001 MAIK “Nauka/Interperiodica”.
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