IMPLICATION OF CENTRAL COMPOSITE DESIGN IN THE DEVELOPMENT OF SIMVASTATIN-
LOADED NANOSPONGES
Original Article
SADHANA NOOTHI
1,2
, NARENDER MALOTHU
1*
, ANKARA ARETI
1
, PRASANNA KUMAR DESU
1
, SARVAN KUMAR
3
1
KL College of Pharmacy, Koneru Lakshmaiah Education Foundation, Vaddeswaram, AP, India.
2
Department of Pharmaceutical
engineering, B V Raju institute of technology, Narsapur, Medak, Telangana, India.
3
Department of Pharmacology, G Pulla Reddy College of
Pharmacy, Hyderabad, Telangana, India
*
Corresponding author: Narender Malothu;
*
Email: narendermalothu@gmail.com
Received: 28 May 2023, Revised and Accepted: 03 Jul 2023
ABSTRACT
Objective: The present study’s objective was to apply a central composite design to develop the simvastatin-loaded nanosponge formulation to
improve its oral bioavailability.
Methods: With the help of a design expert (State-Ease version 13.0.1), a central composite design was selected for the formulation of simvastatin-
loaded nanosponges by using a defined concentration of Eudragit L-100 (X1) and PVA (X2) as independent variables and particle size (Y1), percent
(%) entrapment efficiency (EE) (Y2), in vitro drug release (Y3) as dependent variables. Fourteen (SF1-SF14) formulations were prepared using the
emulsion solvent evaporation and evaluated for surface morphology, particle size, drug-excipient compatibility, %EE, and % drug release. The
optimized model (SF14) obtained from a design expert was evaluated for in vivo pharmacokinetics in animal models.
Results: SF14 was formulated and evaluated for morphology (shape and size) of the particle, % EE, in vitro % drug release, and its kinetics. The
formulation showed particle size of 163±0.45 nm, 80.54 %±0.57 of EE, and 97.13%±0.38 of drug release at 8h. The release kinetics followed the
zero-order and Higuchi mechanisms with non-fiction diffusion. In vivo results showed Cmax, Tmax, AUC0-t, AUC0-α, and MRT0-α for nanosponges were
0.175 µg/ml, 6 h, 1.561 µg/mlh, 1.755 µg/mlh, 11.77 h, respectively.
Conclusion: The results indicated a significant increase in the bioavailability of the drug in nanosponges compared with standard drugs. The
experimentally designed nanosponge formulations have been successfully developed, and evaluated parameters show that the nanosponge
formulation of Simvastatin is a promising delivery through the oral route.
Keywords: Nanosponges, Eudragit L-100, Surface response method, Particle size, Central composite design
© 2023 The Authors. Published by Innovare Academic Sciences Pvt Ltd. This is an open access article under the CC BY license (https://creativecommons.org/licenses/by/4.0/)
DOI: https://dx.doi.org/10.22159/ijap.2023v15i5.48453. Journal homepage: https://innovareacademics.in/journals/index.php/ijap
INTRODUCTION
Due to its ease of administration and patient compliance, the
conventional drug delivery method is a frequently utilized strategy
for various medications. However, it has a few drawbacks, like dose
frequency, narrow therapeutic index, and fluctuations [1]. Different
advanced drug delivery systems, like controlled, sustained, and
targeted delivery, including nanotechnology, was focused on
enhancing the solubility and improving the release characteristics of
drug molecules [2]. Novel drug delivery systems are being used to
improve or enhance the bioavailability of the drug and deliver the
drug released at a specific site. Nanosponge technology is a novel
emerging approach to improving the solubility and bioavailability of
poorly water-soluble drugs [3, 4].
Nanosponges are one of the novel formulations in recent trends of
nano-drug delivery. Nanosponges can be able to entrap both water-
soluble and insoluble drugs. These are non-toxic, porous, stable at
high temperatures, and insoluble in water and organic solvents [5-
7]. These nanosponges circulate throughout the body, approach the
desired location, and release the medication in a planned and
controlled manner during parenteral administration.
Hyperlipidaemia is an acquired disorder defined as elevated lipid
levels in the body, including HDL, LDL, and VLDL, caused due to diet
and genetics [8, 9]. Simvastatin (SIM) is a lipid-lowering drug
belonging to the statins class used to lower abnormal lipid levels and
reduce the risk of cardiovascular disease by inhibiting cholesterol
production in the liver. SIM has less bioavailability (5%) due to low
solubility, short half-life (1.9 h), and protein binding is 95% [10, 11].
Due to low solubility and less half-life, and high protein binding
(>95%), conventional release formulations may cause adverse
events of HMG-CoA reductase inhibitor activity [12].
Novel formulations like liposomes, niosome, liquid crystals, and
nanoparticles are formulated [13] to improve solubility and hepatic
availability. Nanosponge is also one of the novel formulations. As per
recent reports, a few studies achieved the nanosponge formulations by
employing ethyl cellulose, Eudragit S-100 [14] as rate retardant
polymers with cyclodextrin [15] and polyvinyl alcohol (PVA) as
copolymer. In our earlier studies, we tried to develop a nanosponge of
SIM with ethyl cellulose by claiming this technology [16]. However, we
have noticed low entrapment efficiency (%EE) with the use of ethyl
cellulose combination with PVA. To produce a superior nanosponge
formulation, an experimental design approach was adapted by
considering two independent variables i.e., Eudragit L-100 as a rate
retardant polymer and PVA as a copolymer for the formulation of
nanosponges. The formulated nanosponges were evaluated for size,
%EE, in vitro, in vivo drug release, and release kinetics [17, 18].
MATERIALS AND METHODS
Materials
Hetero Drugs, Hyderabad, provided a complimentary sample of SIM
and Eudragit-L100. Polymers like PVA, solvents, and other chemicals
were procured from SD Fine Chemicals, Mumbai. All chemicals used
were analytical grade.
Implication of quality by design (QbD) concept
QbD is a systematic approach to drug development that emphasizes
understanding the critical process and product parameters that
affect product quality and designing a formulation and
manufacturing process that ensures consistent quality [19, 20].
When applied to the formulation of SIM nanosponges, QbD can have
several implications. QbD can help to select the appropriate raw
materials for the nanosponge formulation. By understanding the
impact of each raw material on the final product quality, one can
choose the most suitable materials to ensure consistent product
quality. The steps involved in this procedure include i. identification
of Critical Quality Attributes (CQAs) for SIM nanosponges ii. Defining
International Journal of Applied Pharmaceutics
ISSN- 0975-7058 Vol 15, Issue 5, 2023