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Materials Today: Proceedings 17 (2019) 261–265 www.materialstoday.com/proceedings
2214-7853 © 2019 Published by Elsevier Ltd.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Advanced Materials, Energy &
Environmental Sustainability, ICAMEES2018
ICAMEES 18
Effect of Annealing on Structure, Optoelectronic and
Photoresponsivity Properties of Sol-gel Prepared ZnO Nanoparticles
Prashant Kumar Mishra
1
, Somaditya Sen
2,*
, Ruhul Amin
3
, Sajal Biring
4
1, 2*, 3
Discipline of Physics, Indian Institute of Technology Indore, Khandwa Road, Indore - 453552, India
4
Dept. of Electrical Engg., Ming Chi University of Technology, New Taipei, Taiwan
Abstract
ZnO is successfully synthesized by sol-gel synthesis route. These are analyzed by XRD, FESEM, and UV Sensing
measurements. XRD indicates a polycrystalline nature with appreciable crystallinity. Changes in band structure and defect states
are also discussed. Defect states are found to increase with annealing temperature and hence increase in oxygen related defects
also noticed. Photocurrent decreases with annealing temperature. It may have wide applications in UV-sensors, UV filters, ad UV
absorptive membranes etc.
© 2019 Published by Elsevier Ltd.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Advanced Materials, Energy &
Environmental Sustainability, ICAMEES2018
Keywords: Sol-gel, Annealing, Defects, Oxygen vacancies, UV-sensing
1. Introduction
ZnO is low cost chemically stable semiconductor material with excellent optoelectronic, sensing and morphological
properties. Owing to this it has got diverse applications as in lasers, light-emitting diodes, nano-sensors, and solar
cells [1]. ZnO is n-type with wide bandgap ~3.37 eV and, exciton binding energy ~60meV which makes it a
competitive optoelectronic material to GaN [2-3].There are many reports on the thermal treatment of ZnO under
various annealing conditions such as temperature, environments, to improve the optical properties of ZnO [4].In
present work, structural, morphological, optoelectronic and photo-sensing characteristics have been studied for ZnO
nanoparticles annealed at different temperatures. Effects of annealing on defects states, UV-sensing and co-relation
between them are discussed.