Nutrient Recovery by Struvite Crystallization Process: Virginia Experience
Ram Prasad,
1
Ahren Britton,
2
Bill Balzer
3
, Gary Schafran
1
1: Old Dominion University
Rm 135 Kaufman Hall, Hampton Blvd
Norfolk, Virginia 23529
2: Ostara Nutrient Recovery Technologies Inc. 3: Hampton Roads Sanitation District
ABSTRACT
The Hampton Roads Sanitation District's (HRSD), Nansemond Treatment plant (NTP)
services the cities of Chesapeake, Portsmouth and Suffolk, Virginia. The plants treated effluent
is discharged into the Chesapeake Bay watershed. The NTP was designed as a 30 MGD
biological nutrient removal (BNR) plant with seasonal nitrification and utilizes anaerobic
digestion for solids stabilization and centrifugation for dewatering. Centrate containing high
levels of phosphorus (up to 900 mg P/L) and ammonia (~700 mg N/L) is returned to the plant
headwork and contributes significantly to the BNR process loading. The high loading of these
nutrients is a potential cause of instability to the treatment process leading to spikes in the
secondary effluent phosphorus concentrations as well as reducing plant nitrification and
denitrification capacities. During these periods, metal salts (FeCl
3
) have been intermittently
required to precipitate phosphorus to achieve compliance. Precipitating phosphorus is quite
effective, but this option is not considered as a sustainable solution for phosphorus removal due
to the high costs of chemicals, solids handling and disposal.
The formation of struvite (MgNH
4
PO
4
· 6H
2
O) has recently been commercialized as a treatment
process for phosphorous and ammonia recovery from sludge dewatering sidestream and is being
considered for treating centrate at the NTP. A pilot scale struvite crystallization process (Ostara
Nutrient Recovery Technologies Inc.) has been operating at the NTP from October 2006 to
March 2007 to determine the feasibility of the process for full scale implementation at this site.
Centrate fed to the pilot reactor typically measures 300-700 mg/L phosphate-P and 820 mg/L
ammonia-N. Over the course of the pilot demonstration, phosphorous removal averaged 85%
while ammonia removal ranged from 35 to 50%. A full scale struvite recovery process, currently
being evaluated, would reduce loading in the main liquid process train by approximately 500 lbs
PO
4
-P/day and 250 lbs NH
4
-N/day in addition to providing diurnal centrate flow equalization.
KEYWORDS
Struvite, Nutrient Recovery, Crystallization, fluidized bed reactor.
INTRODUCTION
The Nansemond Treatment Plant (NTP), operated by the Hampton Road Sanitation District
(HRSD), services the Cities of Portsmouth, Chesapeake, Suffolk and Isle of Wight County and
town of Holland in Virginia, and ultimately discharges treated effluent to the Chesapeake Bay
watershed. It is a 30 MGD design capacity biological nutrient removal (BNR) plant using the
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