Pergamon
Solid State Communications, Vol. 98, No. 4, pp. 321-326, 1996
Copyright © 1996 Published by Elsevier Science Ltd
Printed in Great Britain. All rights reserved
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S003S-1098(96)00042-7
AC Susceptibility Study Of Ce(Feo.9AIo.02
S. Mukherjee, R. Ranganathan
Low Temperature Physics"Section,
Saha hlstitute of Nuclear Physics,
1/AF Bidhannagar,
Calcutta 700 064, bsdia
S.B. Roy
Low Temperature Physics Group,
Centre for Advanced Technology,
bldore 452012, hldia
(Received 29 September 1995; accepted 5 January 1996 by C.N.R. Rao)
Linear and non linear AC Susceptibilities have been experimentally investigated
for Ce(Feo.9AI0.1)2. The results suggest that suppression of domain wall motion is
responsible for the observed AC Susceptibility behaviour. The observed cusp in AC
Susceptibility has nothing to do with the cusp observed in SG systems, eventhough
there is a coexistence of ferromagnetic and antiferromagnetic phases with competing
interactions in the present system. An attempt has been made to explain the different
natures of the AC Susceptibility behaviours for different AI concentrations in the
CeFe2 system by comparing with AI (4%) data.
Introduction :-
Anomalous behaviour of the Cubic Laves phase
intermetallic compound CeM 2 (M = Fe, Co, Ni) in
comparison with other RM 2 compounds ( R = Rare earth
element) has been explained by 3d - 4f hybridization I
CeFe~, extensively studied among the CeM 2 group is found
to show ferromagnetism below T c - 230 K with a saturation
magnetization of 2.3 la a per formula unit 2. Spin polarized
calculations by Eriksson et al. predict spin moments on both
Fe and Ce sites with the Ce moment (an almost equal
mixture of 4f (-0.4 lat0 and 5d (-0.3 laB) contributions)
aligned antiparallel to the Fe moment (1.43 law) 1. At 10 K
the polarized neutron scattering results confirm their
prediction with different values for magnetic moments 3.
Neutron diffraction studies by Kennedy and Coles
suggest a tendency towards AFM ordering even in the
parent compound CeFe2 and the substitution of metallic
impurities such as AI enhances this tendency. There are no
contributions from the Ce moment in the ferromagnetic
phase of Ce(Fel.xAIx) 2 with (x --- 0.02 - 0.08). Below x =
0.08, ferromagnetic order occurs in the compounds Ce(Fe~.
~AI~) 2. As we increase the AI concentration, To, i.e. the
temperature at which the ferromagnetic component appears,
decreases. However TN, i.e. the temperature at which the
AFM component appears, increases. The overlapping region
of two distinct magnetic phases results in the existence of a
canted phase 4. A non-collinear arrangement of magnetic
moments has been suggested to explain the magnetization
behaviour of Ce(Fel.xAlx)2 5. For Ce(Feo.92A10.os)2, a region
of canted phase characterized by the lack of saturation of
magnetization and magnetoresistance even in an applied
field of 5 T has been observed 6
Below x = 0.05 AC Susceptibility (ACS) and
magnetization behaviour show features commonly observed
in RSG systems. Macroscopic properties of many systems
(RSG, Canted) with very different microscopic backgrounds
may show some common features as their bulk properties
are determined by some common mechanisms (e.g. pinning
of domain wall motion), although the origin of these
common mechanisms might be quite different. For AI (4*/,)
these aspects have been discussed in detail from the linear as
well as nonlinear ac susceptibility point of view 7. For AI
(10%) a preliminary measurement of AC Susceptibility has
been reported 8 We wish to emphasize that the general
nature of the AC Susceptibility curve is very different
from that obtained for AI (4%). But the origin of this
nature in the context of increasing A1 concentration in
Ce(Fei.xAl~) z has not been very clear although it is very
important for a clear understanding of the system from
the nmcrascopic point of view. This motivates us to
investigate the system in detail from linear as well as
nonlinear ACS point of view under different experimental
conditions (i.e. z(hac, co, HDc)). Regarding nonlinear studies
it has been found that for AI (4%) the nonlinear ACS
behaviour is similar to that observed in SG/RSG systems
even though AI (4%) is a canted system. We have extended
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