American Journal of Materials Science 2017, 7(6): 232-239
DOI: 10.5923/j.materials.20170706.02
Ceramic Filters Impregnated with Silver Nanoparticles
for Household Drinking Water Treatment
Ahmed A. Moosa
*
, Maryam F. Muhsen
Department of Materials Engineering Technology, Engineering Technical College-Baghdad, Middle Technical University Baghdad, Iraq
Abstract Silver nanoparticles (AgNPs) were synthesized from biological materials (Ziziphus plant) under microwave
irradiation and later theses AgNPs were used for the reduction of microbial effect in water. Fourier Transformation infrared
Spectroscopy (FTIR), UV-Vis spectrophotometer and Atomic Force Microscopy (AFM) were used to characterize AgNPs.
Process parameters that affect the AgNPs synthesis, such as AgNO
3
concentration, microwave exposure time, amount of
extract volume and pH of the solution were also studied. The best average diameter of AgNPs (80 nm) showed by AFM.
Ceramic filter and tablets were prepared from local Iraqi clay which is mixed with different combustible material (date palm
seed, sawdust and charcoal). The maximum apparent porosity (50.52% porosity) was obtained at a mixing ratio of clay:
charcoal of 10:4. Total Bacteria Count (TBC) was measured in the filtered water and gave a result of 0.001 CFU/ml which
shows that silver nanoparticles have excellent antimicrobial activity.
Keywords Ceramic filter, Silver Nanoparticles, Green synthesis, Ziziphus Spina Christi, AFM, Ceramic tablets
1. Introduction
Safe drinking water and sanitation are fundamental to
health, survival, growth and development (Montgomery and
Elimelech 2007) [1]. However, these basic necessities are
still a luxury for many people worldwide. Over 1.1 billion
of world citizens do not use safe drinking water, while 2.6
billion lack basic sanitation. In the developing countries,
millions suffer from preventable illnesses and die every
year because of the lacking of water and sanitation services
(WHO: Geneva 2006) [2].
An estimated 1.8 million deaths occur each year because
of a lack of access to safe water, sanitation, and proper
hygiene, of which 99.8% occur in developing countries and
90% are children (Nath et al. 2006) [3]. These deaths can be
reduced with proper infrastructure and education.
Water is certainly the most valuable natural resource,
encompass over 70% of the earth’s surface. Nevertheless,
the demand for clean water is a worldwide, whether it is
for human consumption, agricultural uses, or industrial
uses (Cicek 2003) [4]. The United Nation Millennium
Development Goals (MDG) in 2002, stressed the issue of
water and sanitation on the global agenda. The MDG vision
is to reduce halve the number of people without access to
safe drinking water and sanitation by 50% by the year 2015
* Corresponding author:
ahmeda1752@yahoo.com (Ahmed A. Moosa)
Published online at http://journal.sapub.org/materials
Copyright © 2017 Scientific & Academic Publishing. All Rights Reserved
(WHO and UNICEF 2010) [5]. But up to date over half a
billion people worldwide still lack access to drinking water
from improved sources.
Ceramic water filters manufactured with local labor using
clay and a combustible organic material are one of the most
promising point-of-use water-treatment technologies.
The-pot-shaped filter is placed in a larger, plastic container
with a spigot to also provide a safe-storage reservoir
(Kallaman et al. 2011) [6].
Green synthesis of AgNPs using plant extracts is a cost
effective method, environment friendly, and no toxic
chemicals used (Thakkar et al. 2010) [7]. Silver
nanoparticles have been synthesized using various plants.
(Moosa et al., 2015) [8] used spent tea leaves extract to
synthesizing AgNps which was confirmed by changing
their color to dark brown due to surface plasmon resonance
(SPR) phenomenon. (Moosa et al., 2015) [9] synthesized
silver nanoparticles (AgNPs) using Aloe Vera plant leaves
extract act as reducing and stabilizing agent.
The aim of this work is to prepare silver nanoparticles
(AgNPs) by green synthesis methods using Ziziphus Spina
Christi leaves extract as a common Iraqi plant. Different
parameters that affect the AgNPs preparation such as
temperature, pH, AgNO
3
and plant extract concentrations
will be studied. To make ceramic water filter from Iraqi
clay using different percentage of burnable materials such
as (rice husk, sawdust or others) and study the porosity,
water flow of these ceramic water filters. And make
ceramic tablets from Iraqi clay and then impregnate these
tablets with silver nanopaticles.