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Materials Today: Proceedings 5 (2018) 15710–15716 www.materialstoday.com/proceedings
2214-7853 © 2018 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of INN International Conference/Workshop on “Nanotechnology and Nanomedicine’’
NTNM2017.
NTNM2017
Mechanical and piezoelectric characterizations of electrospun
PVDF-nanosilica fibrous scaffolds for biomedical applications
Seyyed Arash Haddadi, Saeed Ghaderi, Majed Amini, Ahmad Ramazani S.A.
*
a
Chemical & Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
Abstract
The effects of hydrophilic and hydrophobic nanosilica (SiO
2
) on the morphology, mean diameter distribution of fibers,
mechanical and piezoelectric properties of poly (vinylidene fluoride) (PVDF) nanofibers were studies. We prepared Nanofibers
by the electrospinning of PVDF solutions containing 1.5 wt. % both hydrophilic and hydrophobic nano-SiO
2
loadings.
Morphology and diameter distribution of the electrospun nanofibers were studied using field emission scanning electron
microscopy (FE-SEM) analysis. Tensile test was used to study the effect of both types of nanosilica on the tensile strength,
young’s modulus and strain at break. Piezoelectric characterization of the electrospun fibers were determined using calculation of
the output voltages under certain loading force. Results showed that the fibers diameter and mechanical properties of the
nanofibers increase in presence of hydrophilic SiO
2
nanoparticles. Furthermore, the output voltages of the electrospun fibers
demonstrated that both types of silica could considerably amplify electroactive properties of PVDF fibers. However, the results
for PVDF fibers containing the hydrophilic silica nanoparticle were more highlighted.
© 2018 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of INN International Conference/Workshop on “Nanotechnology and Nanomedicine’’
NTNM2017.
Keywords: Piezoelectric; Nanosilica; Poly(vinylidene fluoride); Scaffold; Biomedical applications
1. Introduction
Poly (vinylidene fluoride) (PVDF) with a simple chemical formula, -CH
2
-CF
2
-, has useful special properties such
as the remarkable antioxidation, outstanding mechanical properties, high chemical resistance, maintaining cellular
* Corresponding author. Tel.: +9821-66166405; Fax: +9821-66166404.
E-mail address: ramazani@sharif.edu