* Corresponding author: Elsherif, Khaled Muftah
E-mail: elsherif27@yahoo.com
© 2024 by SPC (Sami Publishing Company)
Advanced Journal of Chemistry, Section A
journal homepage: www.ajchem-a.com
Original Research Article
Adsorption of Cd(II) onto Olive Stones Powder Biosorbent:
Isotherms and Kinetic Studies
Khaled Muftah Elsherif
1
* , Rima Abdessalem Abdullah Saad
2
, Abdunaser Mabrok Ewlad-
Ahmed
2
, Abdullah Amhimmid Treban
2
, Abdulrhman Mohammed Iqneebir
2
1
Libyan Authority for Scientific Research, Tripoli, Libya
2
Chemistry Department, Faculty of Arts and Science Msallata, ElMergib University, Al-Khoms, Libya
A R T I C L E I N F O
A B S T R A C T
Article history
Submitted: 11 September 2023
Revised: 08 October 2023
Accepted: 30 October 2023
Available online: 31 October 2023
Manuscript ID: AJCA-2308-1415
Checked for Plagiarism: Yes
Language editor:
Dr. Fatimah Ramezani
Editor who approved publication:
Dr. Milad Ghani
DOI: 10.48309/AJCA.2024.415865.1415
Cadmium (Cd) is a hazardous heavy metal that presents substantial hazards
to both human well-being and the ecosystem. To address this issue,
biosorption, an environmentally friendly and cost-effective technique, utilizes
biological materials to capture metal ions from contaminated water. In our
research, we focused on developing a biosorbent material using olive stones
powder (OSP), which is a readily available agricultural waste. Our study
aimed to assess the OSP effectiveness in the process of extracting Cd(II) ions
from various aqueous solutions under diverse experimental parameters. In
addition, we examined the adsorption kinetics and isotherms using various
models. The findings revealed that OSP exhibited a strong adsorption capacity
and affinity for Cd(II) ions, with a maximum value of 20.245 mg/g achieved at
pH 6, an OSP dosage of 0.05 g, and a contact time of 30 minutes. The
adsorption process adhered to the pseudo-second-order kinetic model and
conformed to the Freundlich isotherm model, indicating the formation of
multiple layers and the presence of heterogeneous surface sites. Furthermore,
comparing the maximum capacity value (Qm) of OSP obtained in our study
with previous research, it falls within the intermediate range. Overall, our
study demonstrated the potential of OSP as a highly effective biosorbent
material for effectively eliminating Cd(II) ions from aqueous solutions.
K E Y W O R D S
Adsorption
Cadmium
Olive stones
Isotherms
Kinetics
Advanced Journal of Chemistry, Section A, 2024, 7(1), 59-74