Research Article
Characterization of Nanosilica/Low-Density Polyethylene
Nanocomposite Materials
Malek Alghdeir , Khaled Mayya, and Mohamed Dib
Applied Physics Department, Higher Institute for Applied Sciences and Technology, Damascus, Syria
Correspondence should be addressed to Malek Alghdeir; malekghdeir@yahoo.com
Received 2 October 2018; Revised 22 November 2018; Accepted 19 December 2018; Published 20 March 2019
Guest Editor: Chandragiri V. Reddy
Copyright © 2019 Malek Alghdeir et al. This is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Six ratios of nanosilica particles were employed to fabricate low-density polyethylene (LDPE) composites using melt mixing
and hot molding methods. Several composite films with different ratios (0.5, 1, 2.5, 5, 7.5, and 10 wt%) of SiO
2
were
prepared. The obtained composite films were identified and characterized by Fourier-transform infrared spectroscopy (FTIR)
and ultraviolet-visible spectroscopy (UV-VIS). At a specific mixing ratio, far infrared radiation transmittance was prohibited
while the ultraviolet-visible transmittance is allowed; this will be explained in detail. Optical measurements show that the
composite films prevent the transmission of IR radiation near 9 μm and allow UV-VIS transmission during sun-shining time.
The mechanical behaviour of a nanosilica-reinforced LDPE composite was studied using tensile tests. The addition of 1 wt%
nanosilica has successfully enhanced the mechanical properties of the LDPE material.
1. Introduction
Polymeric materials are widely used in food packaging and
in greenhouses. Typical examples of such materials are
polypropylene (PP), polyethylene (PE), and polyethylene
terephthalate (PET) [1, 2].
During the past years, much effort has been devoted to
polymer nanocomposites [3]. Polymer nanocomposites
often show excellent mechanical properties compared to
the traditional composites at a lower loading of the nanopar-
ticles [4]. So far, a few researches have studied the effects of
different nanoparticles on the performances of composite
materials such as nanosilica [3]. The excellent performance
of silica film has attracted attention in academia and indus-
try due to its antiresistance, hardness, corrosion resistance
[5], dielectric properties [6], optical transparency, etc. [7].
Silica as a thin film is widely used to improve the surface
properties of materials. This is why silica thin films are used
in many fields as in antireflection coating film field [8]. In
the packaging industry, silica films are used as barrier layers
in polymer packaging materials. Most of the modern pack-
aging materials do not provide an efficient barrier against
the permeation of gases. This leads to food and drinks
getting rotten quickly. Because of this, a silica film deposited
on the surface of the polymer packaging becomes popular
and indispensable. Besides, silica films can be also used as
corrosion protective layers of metals. Because of the univer-
sal application of silicon dioxide films in various fields, the
preparation of silica with high quality is always an important
aim of scientific research [9].
Lately, a number of different barrier technologies were
being developed. Theoretically, a barrier function can be
inserted into a plastic-based material via two different means:
either by mixing a barrier material into the base polymer or
by coating a layer of the barrier material on the polymer
surface [10, 11].
The traditional method of preparing polymer/silica
composites was direct mixing of the silica into the polymer.
The mixing could be done by melt blending and solution
blending. The main difficulty in the mixing process is the
effective dispersion of the silica nanoparticles in the polymer
matrix, because they usually tend to agglomerate [12].
This work represents the results of optical and thermal
experiments on LDPE mixed with nanosilica particles at
different ratios (0.5, 1, 2.5, 5, 7.5, and 10 wt%). The aim is
to achieve a nanocomposite that prevents the transmittance
Hindawi
Journal of Nanomaterials
Volume 2019, Article ID 4184351, 8 pages
https://doi.org/10.1155/2019/4184351