© Korean Powder Metallurgy Institute
- 1249 -
1. Introduction
In YBCO coated conductors (CC) process, multi-buffers
and YBCO layer should be epitaxially deposited on
substrate, thus, the formation of the substrate texture is
critical to improve the critical current.
Two different approaches were used to fabricate textured
metal in terms of preparation of initial specimens, i.e.,
casting and powder metallurgy (P/M). The casting method
is simpler and provides denser and larger ingots than the
P/M method. Most of the published researches deal with the
casting method rather than with P/M[1]. By contrast, the
P/M method has the advantages of forming a high purity
microstructure without columnar or dendrite structure and
of ease in making alloys with uniformly distributed
elements. While it is well known that the texture depend on
the annealing temperature and total reduction ratio, the
texture components and their variation in the Ni substrate
prepared by the P/M method were not widely studied.
In this work, we fabricated Ni substrates by P/M and
casting methods. To characterize the effects of the two
methods, the initial specimens were made of the same size
and subjected to the same rolling conditions. Subsequently,
the effects of annealing temperature and reduction ratio on
the texture and grain morphology were evaluated.
2. Experimental and Results
Ni substrates were fabricated by P/M and casting via
plasma arc melting(PAM) methods. To evaluate the effects
of the two methods, the initial specimens were of the same
size and subjected to the same rolling conditions. In the
P/M method, the Ni powder was loaded into a mold, and
isostatic pressure of 200 MPa was applied to form a
rod-type compact(13 mm diameter and 120 mm length).
The compacts were sintered at 1100 for 6 h in an ℃
atmosphere of 96% Ar and 4% H
2
. For the casting method,
99.99% Ni chips were melted by plasma arc furnace in a
reduced atmosphere of 1 x 10
-3
torr and then formed into a
rod-type ingot(13 mm diameter and 120 mm length).
The Ni rods were then cold-rolled into thin tape by a
two-high rolling mill. Each rolling step reduced the
thickness by less than 5%, and total reduction of 98.6% and
99.2% were incorporated to evaluate variation of texture
with total reduction. Recrystallization annealing was
performed at 600℃-1200 for 30 min. in an atmosphere of ℃
96% Ar and 4% H
2
..
Microstructures were examined by optical microscopy.
The texture of the substrate was measured by four
incomplete pole figures.
In order to evaluate the dependence of texture on the
initial specimens and on the total reduction, a detailed
analysis of ODFs of the rolled tapes was done. For the
P/M-tape, the observed texture was mainly composed of
Cu({112}<111>), Bs({110}<112>), and S({123}<634>)
components. On the other hand, texture of the casting-tape
consisted of Cu, Bs, S, and {013}<100> component as the
major texture component and {110}<113>, {012}<121>,
{012}<112>, and {001}<110> as minor one. The ODF of
2006 POWDER METALLURGY
World Congress
PC14-W-08
Texture Evolution in Ni Substrate Prepared by Powder Metallurgy and Casting
Methods
Jun Hyung Lim
1
, Kyu Tae Kim
1
, Eui Cheol Park
1
, Jinho Joo
1, a
, Hyoungsub Kim
1
, Hoo-Jeong Lee
1
,
Seung-Boo Jung
1
, and Wansoo Nah
2
1
School of Advanced Materials Science and Engineering, Sungkyunkwan University
300 Cheoncheon, Jangan, Suwon, Gyeonggi, Korea
2
School of Electrical and Computer Engineering, Sungkyunkwan University
300 Cheoncheon, Jangan, Suwon, Gyeonggi, Korea
a
jinho@skku.edu
Abstract
Cube textured Ni substrate were fabricated for YBCO coated conductors from the initial specimens prepared by powder
metallurgy (P/M) and casting and the effects of annealing temperature and reduction ratio on texture formation and
microstructural evolution were evaluated. The initial specimens were rolled and then annealed in the temperature at 600℃
~1200℃.
A strong cube texture formed for P/M substrate, and the degree of texture did not significantly vary with annealing
temperature of 600℃~1100℃. On the other hand, the texture of casting substrate was more dependent on the annealing
temperature and twin texture and several minor texture components started to form at 1000℃.
Keywords : Casting, Cube texture, powder metallurgy, substrate, YBCO