LETTERS PUBLISHED ONLINE: 2 MAY 2016 | DOI: 10.1038/NPHYS3743 Quantum phase transitions with parity-symmetry breaking and hysteresis A. Trenkwalder 1 , G. Spagnolli 2 , G. Semeghini 2 , S. Coop 2,3 , M. Landini 1 , P. Castilho 1,4 , L. Pezzè 1,2,5 , G. Modugno 2 , M. Inguscio 1,2 , A. Smerzi 1,2,5 and M. Fattori 1,2 * Symmetry-breaking quantum phase transitions play a key role in several condensed matter, cosmology and nuclear physics theoretical models 1–3 . Its observation in real systems is often hampered by finite temperatures and limited control of the system parameters. In this work we report, for the first time, the experimental observation of the full quantum phase diagram across a transition where the spatial parity symmetry is broken. Our system consists of an ultracold gas with tunable attractive interactions trapped in a spatially symmetric double-well potential. At a critical value of the interaction strength, we observe a continuous quantum phase transition where the gas spontaneously localizes in one well or the other, thus breaking the underlying symmetry of the system. Furthermore, we show the robustness of the asymmetric state against controlled energy mismatch between the two wells. This is the result of hysteresis associated with an additional discontinuous quantum phase transition that we fully characterize. Our results pave the way to the study of quantum critical phenomena at finite temperature 4 , the investigation of macroscopic quantum tunnelling of the order parameter in the hysteretic regime and the production of strongly quantum entangled states at critical points 5 . Parity is a fundamental discrete symmetry of nature 6 conserved by gravitational, electromagnetic and strong interactions 7 . It states the invariance of a physical phenomenon under mirror reflection. Our world is pervaded by robust discrete asymmetries, spanning from the imbalance of matter and antimatter to the homo-chirality of DNA of all living organisms 8 . Their origin and stability is a subject of active debate. Quantum mechanics predicts that asymmetric states can be the result of phase transitions occurring at zero temperature, named in the literature as quantum phase transitions (QPTs) 1,4 . The breaking of a discrete symmetry via a QPT provides also asymmetric states that are particularly robust against external perturbations. Indeed, the order parameter of a continuous-symmetry-breaking QPT can freely (with no energy cost) wander along the valley of a ‘mexican hat’ Ginzburg–Landau potential (GLP) by coupling with gapless Goldstone modes 9 . In contrast, the order parameter of discrete-symmetry-breaking QPTs is governed by a one-dimensional double-well GLP 10 . The reduced dimensionality suppresses Goldstone excitations, and the order parameter can remain trapped at the bottom of one of the two wells. This provides a robust hysteresis associated with a first-order QPT. Evidence of parity-symmetry breaking has been reported in relativistic heavy-ions collisions 11 and in engineered photonic crystal fibres 12 . Observation of parity-symmetry breaking in a QPT has been reported for neutral atoms coupled to a high-finesse optical cavity 13 . However, this is a strongly dissipative system, with no direct access to the symmetry-breaking mechanism necessary to study the robustness of asymmetric states. In addition, previous theoretical studies 14,15 have interpreted the puzzling spectral properties of a gas of pyramidal molecules that date back to the 1950s (ref. 16), in terms of the occurrence of a QPT with parity-symmetry breaking. In the present work we report the observation of the full phase diagram across a QPT where the spatial parity symmetry is broken. Our system consists of ultracold atoms trapped in a double-well potential 17,18 where the tunable strength of the attractive interparticle interaction is the control parameter of the transition. Additional control of the energy mismatch between the two wells allows driving of discontinuous first-order QPTs in the non- symmetric ordered part of the phase diagram and observation of an associated hysteretic behaviour. In our system, the atomic ground state depends on two competing energy terms in the Hamiltonian H = H a + gH b , where H a = dr (r)[−( ¯ h 2 /2m) 2 + V (r)](r) includes kinetic and potential energy, and H b = (2π ¯ h 2 a 0 /m) dr (r) (r)(r)(r) accounts for contact interaction between the atoms. Here, (r) is the many-body wavefunction, (r) its hermitian conjugate (in the following we consider normalization (r)(r)〉= 1), m the atomic mass, a 0 is the Bohr radius, ¯ h the reduced Planck constant and V (r) is a double-well trapping potential in the x direction (see Fig. 1a) and a harmonic trap in the orthogonal plane. The adimensional control parameter g = Na s /a 0 < 0 is the product of the total number of atoms N and the scattering length a s < 0 characterizing the interatomic attractive interaction. The full many- body Hamiltonian is invariant under x ↔−x mirror reflection. This parity symmetry imposes a spatially symmetric ground state for any value of the control parameter g . Because H a and H b do not commute, the corresponding ground states are quite different. H a is minimized by each atom equally spreading on both wells. A finite energy gap, specified as the tunnelling energy J , separates the ground and the first (antisymmetric) excited state of H a . J can be tuned by controlling the height of the potential barrier between the two spatial wells. In contrast, gH b is minimized by a linear combination of two degenerate states, one having all atoms localized in one well, the second with all atoms localized in the other well. Thanks to the competition in the Hamiltonian between the effective repulsion due to the kinetic energy and the attractive interatomic interaction, the energy gap between the two low-lying © Macmillan Publishers Limited . All rights reserved 1 Istituto Nazionale di Ottica-CNR, 50019 Sesto Fiorentino, Italy. 2 LENS European Laboratory for Nonlinear Spectroscopy, and Dipartimento di Fisica e Astronomia, Università di Firenze, 50019 Sesto Fiorentino, Italy. 3 ICFO-Institut de Ciencies Fotoniques, Barcelona Institute of Science and Technology, 08860 Castelldefels (Barcelona), Spain. 4 Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, 13560-970 São Carlos, São Paulo, Brazil. 5 Quantum Science and Technology in Arcetri, QSTAR, 50125 Firenze, Italy. *e-mail: fattori@lens.unifi.it 826 NATURE PHYSICS | VOL 12 | SEPTEMBER 2016 | www.nature.com/naturephysics