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ISSN 0031-918X, Physics of Metals and Metallography, 2019, Vol. 120, No. 4, pp. 402–409. © Pleiades Publishing, Ltd., 2019.
Published in Russian in Fizika Metallov i Metallovedenie, 2019, Vol. 120, No. 4, pp. 433–441.
Influence of Rare Earths Addition on the Properties of Al–Li Alloys
S. Nazarov
a
, S. Rossi
b
, P. Bison
b
, I. Ganiev
a
, L. Pezzato
c
, and I. Calliari
c,
*
a
Technological University of Tajikistan, Dushanbe, 734061 Republic of Tajikistan
b
CNR-ITC, Padova, 35127 Italy
c
Department of Industrial Engineering, University of Padova, Padova, 35131 Italy
*e-mail: irene.calliari@unipd.it
Received February 12, 2018; revised October 15, 2018; accepted November 12, 2018
Abstract—Aluminum alloys are considered one of the best choices as structural material for aerospace appli-
cations, guaranteeing lightweight and strength at the same time. In this work Al–Li alloys with 6% (wt %) of
Li are used. To increase further the strength of the material, new alloys are produced by adding different
quantities (0.01, 0.05, 0.1, and 0.5 wt %) of rare earths (Nd, Y, Ce, Pr). The microstructure of the samples is
examined using scanning electron microscope (SEM). The improvement of the mechanical properties is
measured by means of Vickers hardness tests. Also the corrosion resistance of the alloys is evaluated with open
circuit voltage (OCV) measurements. At the same time, the thermophysical properties are measured as well,
at various temperatures, from 80 to 500°C. The results show that an increase in the Rare Earth (RE) content
causes an increase in the mechanical properties and a reduction in the thermal conductivity. Regarding the
corrosion resistance, a maximum in the corrosion properties can be found for 0.05% of RE.
Keywords: IR thermography, thermophysical properties, anisotropy evaluation, hardness, corrosion
DOI: 10.1134/S0031918X19040094
INTRODUCTION
The last decade is characterized by the rapid
expansion of the range of new materials as plastics and
composites; however, metals and alloys still remain
the main structural materials in the manufacture of
machinery, equipment, appliances, building con-
struction, transportation, and communications. In
this regard, the improvement of methods to increase
corrosion and mechanical properties is important not
only for the possibility of reducing the economic loss,
but also to provide further technical progress.
The progress in new aerospace structures that
demand improved damage tolerance and weight effi-
ciency leads to the development of a number of inter-
esting alloys. Therefore, the research on Al–Li alloys
has attracted worldwide attention [1, 2].
Aluminum-lithium alloys are a new class of well-
known aluminum systems and are characterized by a
perfect combination of mechanical properties: low
density, high elasticity modulus, and a sufficiently
high strength. The increased interest in the alloying
aluminum with lithium, the lightest metal with a den-
sity of ∼0.54 g/cm
3
, is because each percent of lithium
lowers the density of aluminum of 3% and increases
the Young modulus of about 6%. Lithium is non-toxic
and has desirable precipitation hardening characteris-
tics. The Al–Li alloys have strong anisotropy in
mechanical properties and poor ductility. A possible
mechanism responsible for the Al–Li alloys embrittle-
ment is their high sensitivity to deleterious impurities.
The use of advanced vacuum methods and the addi-
tion of rare earths can be beneficial. The vacuum pro-
cess reduces the level of impurities, whereas the rare-
earth elements can reduce the thermal conductivity
and extend the ductility. It is well known that the addi-
tion of rare earths to Al-based alloys improves tensile
strength, heat resistance, vibration resistance, corro-
sion resistance, and extrudability [3, 4].
This paper presents the results concerning the
effects of rare earth (Ce, Y, Nd, and Pr) addition in the
range 0.01–0.5 wt % on the microstructure and
mechanical properties of cast Al + 6%Li.
The interest in the thermophysical properties of
such new alloys is related mainly to the thermal project
of the aerospace structures. Furthermore, it is quite
interesting to correlate the increased mechanical
properties of the alloys, notably the hardness, with
thermal conductivity that decreases as the hardness
increases. It is therefore worth measuring thermal
properties and their variation at increasing tempera-
tures [5]. This is done for Al + 6%Li with and without
the addition of 0.5% of rare earths (Y and Nd only for
these tests). Finally, the anisotropy of thermal con-
ductivity of such materials is measured by pulsed IR
thermography technique [6, 7] along and perpendicu-
larly to the direction of casting solidification.
STRENGTH
AND PLASTICITY