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Colloids and Surfaces A
journal homepage: www.elsevier.com/locate/colsurfa
Magnetic field induced motion of water droplets and bubbles on the
lubricant coated surface
Pritam Kumar Roy
a
, Edward Bormashenko
a,
*, Mark Frenkel
a
, Irina Legchenkova
a
, Shraga Shoval
b
a
Ariel University, Engineering Faculty, Chemical Engineering, Biotechnology and Materials Department, P.O.B. 3, 407000, Ariel, Israel
b
Ariel University, Engineering Faculty, Department of Industrial Engineering and Management, P.O.B. 3, 40700, Ariel, Israel
GRAPHICAL ABSTRACT
ARTICLE INFO
Keywords:
Wetting
Oil-lubricated surfaces
Magnetic field
Diamagnetic liquid
Bubble
ABSTRACT
Diamagnetic water droplets placed on the silicone-oil-lubricated solid surfaces were displaced by a permanent
magnetic field ≅ B 0.4T. The motion was sensitive to the hydrophobicity of the solid surface. Maximal velocities
≅ − v 0.1 0.2
max
mm
s
were registered on the silicone-oil-lubricated hydrophobic surfaces. The maximal velocities
were insensitive to the volume of water droplets for the volumes in the range of < < V 2 μl 12μl . The maximal
velocities of the droplets were also only slightly dependent on the thickness of the oil layer. A model of the
motion of diamagnetic droplets driven by the permanent magnetic field is suggested. The qualitative model
describes satisfactorily scaling of the experimental findings. The reported process involves purely diamagnetic
materials. Motion of silicone oil bubbles driven by the magnetic field is also reported.
1. Introduction
Magnetic control of displacement of micro- and nano-droplets is a
powerful instrument of the precise control of motion of micro-vessels
that can store chemical reagents, DNA/RNA, proteins and living cells/
microorganisms [1–3]. Magnetic micro- and nano-beads suspended in
the liquid phase are usually used for the magnetically-controlled dis-
placement of micro-vessels [1–3]. We demonstrate that diamagnetic
droplets may be displaced by moderate magnetic fields (∼ 0.4 T) when
placed on oil-impregnated hydrophobic surfaces. Thus, the use of the
ferromagnetic or paramagnetic particles is avoided, which is of a
primary importance for lab-n-chip applications. Wetting of flat and
rough oil lubricated (impregnated) surfaces attracted the attention of
investigators in the last decade [4–13]. Lubrication of solid rough and
flat pre-wetted surfaces is ubiquitous in nature. Cartilage integrity, for
example, is impossible without lubrication [14]. Study of the lubrica-
tion occurring within cartilage inspired the research, and resulted in the
development of efficient artificial lubricants mimicking natural ones
[15]. Artificial lubricant-impregnated surfaces demonstrate the poten-
tial for a diversity of industrial applications. They are obviously at-
tractive for manufacturing omniphobic (superoleophobic) surfaces due
to the fact that they do not suffer from Cassie-Wenzel wetting
https://doi.org/10.1016/j.colsurfa.2020.124773
Received 16 December 2019; Received in revised form 23 March 2020; Accepted 24 March 2020
⁎
Corresponding author.
E-mail address: edward@ariel.ac.il (E. Bormashenko).
Colloids and Surfaces A 597 (2020) 124773
Available online 02 April 2020
0927-7757/ © 2020 Elsevier B.V. All rights reserved.
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