European Reviews of Chemical Research, 2015, Vol.(6), Is. 4 Copyright © 2015 by Academic Publishing House Researcher Published in the Russian Federation European Reviews of Chemical Research Has been issued since 2014. ISSN: 2312-7708 E-ISSN: 2413-7243 Vol. 6, Is. 4, pp. 192-211, 2015 DOI: 10.13187/ ercr.2015.6.192 www.ejournal14.com UDC 541.64:574.24:553.08 The Methods of non-equilibrium Spectrum (NES) and Differential non-equilibrium Spectrum (DNES) in Studying the Interaction of Carbonaceous Mineral Shungite and Aluminosilicate Mineral Zeolite with Water 1 Ignat Ignatov 2 Oleg Mosin 1 Th e Scientific Research Center of Medical Biophysics (SRC MB), Bulgaria Professor, D. Sc., director of SRC MB 1111, Sofia, N. Kopernik street, 32 E-mail: mbioph@dir.bg 2 Moscow State University of Applied Biotechnology, Russian Federation Senior research Fellow of Biotechnology Department, Ph. D. (Chemistry) 103316, Moscow, Talalihina ulitza, 33 E-mail: mosin-oleg@yandex.ru Abstract The mathematical model of interaction with water the amorphous, uncrystallized, fullerene analogous carbon containing natural mineral shungite (Zazhoginskoe deposit, Karelia, Russia) and micro-porous alumosilicate mineral zeolite (Most, Bulgaria) was established. There are submitted data on the nanostructure and structural properties of these minerals, obtained with using the elemental analysis, transmission electron microscopy (TEM-method) and IR-spectroscopy. For evaluation of the mathematical model of interaction of these minerals with water, the methods of non-equilibrium spectrum (NES) and differential non-equilibrium spectrum (DNES) of water were applied. The values of average energy (∆EH...O ) of hydrogen Н…O-bonds among H 2 O molecules in water samples after the treatment of shungite and zeolite with water was measured at -0,1137 eV for shungite and -0,1174 eV for zeolite. The calculation of ∆E H...O for shungite with using the DNES method compiles +0,0025±0,0011 eV and for zeolite -1,2±0,0011 eV. It was demonstrated a regularity of change of energy of hydrogen bonds between H 2 O molecules in the process of water treatment by shungite and zeolite with a statistically reliable increase of local maximums in DNES-spectra. Keywords: shungite, zeolite, nanostructure, fullerens, IR, NES, DNES Introduction Shungite and zeolite – the minerals refer to new generation of natural mineral sorbents (NMS). Shungite is an intermediate form between the amorphous carbon and the graphite crystal, containing carbon (30 %), silica (45 %), and silicate mica (about 20 %) [1]. The schungite carbon is a fossilized organic material of the sea bottom Precambrian sediments of high level of carbonization containing the fullerene-like regular structures. Shungite got its name after the village of Shunga in Karelia (Russian Federation), located on the shore of Onezhskoe Lake, where is 192