Effect of Finishing and Coiling Temperatures on the Nanoprecipitate Dispersion in
Novel HSLA Steels
S Deligiannis
1*
, A Alexandratou
1
, NI Makris
1
, P Tsakiridis
1
and G Fourlaris
1
1.
Lab. of Physical Metallurgy and Center for Electron Microscopy, School of Mining and Metallurgical
Engineering, National Technical University of Athens, H. Polytechniou 9, Athens, Greece.
*Corresponding author: stavrosdel123@gmail.com
High Strength Low Alloy (HSLA) strip steel products are of great importance to the automotive industry,
since they are designed to provide an excellent combination of strength, formability and toughness.
Automotive and steel making producers have carried out research for developing novel high strength strip
steels, focusing on altering alloying compositions as well as the thermomechanical controlled processing
in order to obtain the most desirable mechanical properties [1].
Thermomechanical controlled processing (TMCP) of HSLA strip steels, suitably conditions the steel
microstructure, resulting in a predominantly ferritic microstructure with formation of second phase nano-
precipitates [2]. The influence of these fine precipitates on the overall mechanical properties of a steel
grade, depends on the size, shape and their spatial distributions occurring when altering the TMCP
parameters, such as the finishing temperature (FT), the coiling temperature (CT) or the cooling rates from
FT to CT. Titanium, vanadium and niobium are the most significant micro-alloying elements acting as
carbide and nitride formers, promoting grain refinement and dislocation mobility retardation [2]. In this
study, the materials investigated are two novel experimental model HSLA grades, with controlled overall
alloy compositions, based on titanium only and combined titanium-vanadium additions.
Previous work has confirmed the role of CT on the strengthening for both steel grades and especially on
the Ti-V steel. Moreover, following microstructural investigation, fine precipitation of titanium carbides
and a second precipitation sequence of interphase titanium-vanadium carbides for the Ti-V grade, was
observed [3]. TMCP was carried out using a Gleeble 3500 thermomechanical simulation system and the
treatment applied is depicted in Fig.1. Finishing and coiling temperatures (FT and CT) were considered
as variables, in order to investigate their contribution to the mechanical properties of both steel grades as
well as their effect on the dispersion of second phase carbide nanoprecipitates. For that reason, two
finishing temperatures and three coiling temperatures were employed: FT = 800
o
C and 850
o
C and CT =
550
o
C, 650
o
C and 750
o
C.
The results from the present study highlight that FT, but also CT, play a significant role on the
strengthening sequence of both steel grades. Vickers hardness evolution underlines the fact that Ti-V
samples coiled at 650
o
C present a profound hardening effect, regardless the selected FT (Fig. 2). TEM
investigation confirmed the effect of FT and CT on the microstructures, where, different distributions of
very fine titanium-vanadium carbides for the Ti-V samples were evident (Fig. 3,4). Moreover, slightly
coarser vanadium carbides, randomly dispersed within the ferritic matrix were observed (Fig. 5,6).
References:
[1] D-B Park et al., Mater. Sci. Eng. A 560 (2013), p. 528.
[2] I Tamura et al. in “Thermomechanical Processing of High-strength Low-alloy Steels”, (Butterworth
2656
doi:10.1017/S1431927619014016
Microsc. Microanal. 25 (Suppl 2), 2019
© Microscopy Society of America 2019
https://doi.org/10.1017/S1431927619014016
Downloaded from https://www.cambridge.org/core. IP address: 192.126.161.186, on 07 Aug 2019 at 10:13:08, subject to the Cambridge Core terms of use, available at https://www.cambridge.org/core/terms.